662283

Bis(tert-butylcarbonyloxy)jodbenzol

97%

• Synonym(e): (Di-tert.-butylcarbonyloxyiod)-benzol, 2,2-Dimethylpropionsäure-phenyliodkomplex, Bis(2,2-dimethylpropanoato-O)phenyliodid, Di-(pivaloyloxy)-iodbenzol
• Empirische Formel (Hill-System): C₁₆H₂₃IO₄
• CAS-Nummer: 57357-20-7
• Molekulargewicht: 406.26
• MDL-Nummer: MFCD08276835
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 24884583
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: solid
• Eignung der Reaktion: reagent type: catalyst; reaction type: C-H Activation; reagent type: oxidant
• mp (Schmelzpunkt): 104-109 °C
• Funktionelle Gruppe: iodo
• SMILES String: CC(C)(C)C(=O)O[I](OC(=O)C(C)(C)C)c1ccccc1
• InChI: 1S/C16H23IO4/c1-15(2,3)13(18)20-17(12-10-8-7-9-11-12)21-14(19)16(4,5)6/h7-11H,1-6H3
• InChIKey: DZKPLZUSZXYHFB-UHFFFAOYSA-N

Beschreibung

Anwendung

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Reagent for:

• Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
• Palladium-catalyzed diamination
• Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
• Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
• C-H acyloxylation of arenes

• Hypervalent iodine oxidant

Hypervalent iodine reagent used with the Rh₂(esp)₂ catalyst (662623) in the amination of C-H bonds.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)