419532

2-Methylallylmagnesiumchlorid -Lösung

0.5 M in THF

• Synonym(e): (2-Methyl-2-propenyl)magnesium chloride, Chloro(2-methyl-2-propenyl)magnesium, Chloro(2-methylallyl)magnesium, Methallylmagnesium chloride
• Lineare Formel: H₂C=C(CH₃)CH₂MgCl
• CAS-Nummer: 5674-01-1
• Molekulargewicht: 114.86
• MDL-Nummer: MFCD00674003
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24866258
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: reaction type: Grignard Reaction
• Qualitätsniveau: 100
• Konzentration: 0.5 M in THF
• bp: 65-67 °C
• Dichte: 0.915 g/mL at 25 °C
• SMILES String: CC(=C)C[Mg]Cl
• InChI: 1S/C4H7.ClH.Mg/c1-4(2)3;;/h1-2H2,3H3;1H;/q;;+1/p-1
• InChIKey: BJVFGWYBOLMUEM-UHFFFAOYSA-M

Beschreibung

Anwendung

2-Methylallylmagnesium chloride is a general Grignard reagent used in the synthesis of (−)-aplysin, acutumine, dimedol and allyldicyclopentadienyltitanium(III) complexes.

Verpackung

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Rechtliche Hinweise

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H261,H302,H314,H335,H351
• P-Sätze: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): -5.8 °F - closed cup
• Flammpunkt (°C): -21 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter