391980

1,2,4,5-Tetracyanbenzol

97%

• Synonym(e): 1,2,4,5-Benzoltetracarbonitril, Pyromellitsäure-tetranitril
• Lineare Formel: C₆H₂(CN)₄
• CAS-Nummer: 712-74-3
• Molekulargewicht: 178.15
• Beilstein: 1875027
• MDL-Nummer: MFCD00043481
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24864415
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: solid
• mp (Schmelzpunkt): 265-268 °C (lit.)
• Löslichkeit: acetone: soluble 25 mg/mL, clear, colorless to yellow
• Funktionelle Gruppe: nitrile
• SMILES String: N#Cc1cc(C#N)c(cc1C#N)C#N
• InChI: 1S/C10H2N4/c11-3-7-1-8(4-12)10(6-14)2-9(7)5-13/h1-2H
• InChIKey: FAAXSAZENACQBT-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

1,2,4,5-Tetracyanobenzene (TCNB, TCB) is a tetra substituted benzene. The IR and raman spectra of TCNB and its 1:1 complex with durene has been recorded. The time-resolved linear dichroism spectroscopic study of hexamethylbenzene-1,2,4,5-tetracyanobenzene charge-transfer complex has been investigated. The influence of magnetic field on the charge-transfer fluorescence of 1,2,4,5-tetracyanobenzene-doped poly(N-vinylcarbazole) thin film has been studied.

Anwendung

1,2,4,5-Tetracyanobenzene (TCB, TCNB) is suitable reagent used in the synthesis of o-3,4-dimethyltetrathiafulvalene (o-Me₂TTF)-1,2,4,5-tetracyanobenzene (TCNB) 1:1 complex and radiative exciplexes of TCB in non-polar solvents.

1,2,4,5-Tetracyanobenzene (Pyromellitic acid tetranitrile, PMTN, TCB, TCNB, 1,2,4,5-benzenetetracarbonitrile ) may be used in the following studies:

• Solid-state diffusion of TCNB into 9-methylanthracene molecular crystal nanorods forming cocrystal nanorods.
• Synthesis of copper polyphthalocyanine (CuPPC) thin films, an elementoorganic semiconductor.
• Preparation of charge transfer (CT) nanocrystallites which may have a potential use in nanofluidics to observe the rotational motion of nanoobjects.
• Hydrothermal synthesis of Co₂(terpy)₂(btec)•H₂O (terpy = 2,2′:6′,2"-terpyridine, btec = 1,2,4,5-benzenetetracarboxylate).

Sicherheitshinweise

• Piktogramme: GHS06
• Signalwort: Danger
• H-Sätze: H300,H311 + H331
• P-Sätze: P261 - P264 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Gefahreneinstufungen: Acute Tox. 2 Oral
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges