255920
1,1′-(Azodicarbonyl)dipiperidin
99%
Synonym(e):
ADD, Azodicarbonsäure-dipiperidid
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Alle Fotos(3)
About This Item
Empirische Formel (Hill-System):
C12H20N4O2
CAS-Nummer:
Molekulargewicht:
252.31
Beilstein:
261917
MDL-Nummer:
UNSPSC-Code:
12352005
PubChem Substanz-ID:
NACRES:
NA.22
Empfohlene Produkte
Qualitätsniveau
Assay
99%
Form
solid
mp (Schmelzpunkt)
134-136 °C (lit.)
Funktionelle Gruppe
azo
SMILES String
O=C(\N=N\C(=O)N1CCCCC1)N2CCCCC2
InChI
1S/C12H20N4O2/c17-11(15-7-3-1-4-8-15)13-14-12(18)16-9-5-2-6-10-16/h1-10H2/b14-13+
InChIKey
OQJBFFCUFALWQL-BUHFOSPRSA-N
Anwendung
Reactant for preparation of:
Reactant for:
- Polyfluoroalkylated tripyrazolylmethane ligands
- (-)-Hygromycin A via Mitsunobu glycosylation
- Optically active α,α-disubstituted amino acids via Mitsunobu reaction
- Aza-β-lactams through [2+2] cycloaddition reactions
- Glycosyl disulfides
- Pyridine ether PPAR agonists
- S-glycosyl amino acid building blocks for combinatorial neoglycopeptide synthesis
- Histamine H3 receptor antagonists
Reactant for:
- Mitsunobu inversion reactions
Used in a study of the copper-catalyzed addition of aryboronic acids to azodicarboxyl derivatives providing aryl-substituted hydrazides.
Widely used reagent for the Mitsunobu reaction
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Zielorgane
Respiratory system
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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Dougherty, J.M.; et al.
Tetrahedron, 61, 6218-6218 (2005)
M A Baker et al.
Radiation research, 113(2), 346-355 (1988-02-01)
The mechanism of radiosensitization by diazenedicarboxylic acid bis(N),N-piperidide (SR 4077), a less toxic analog of diamide, was studied using Chinese hamster ovary cells. SR 4077 gave an average SER of 1.58 for postirradiation incubations of 0.5, 1.0, or 2.0 h.
Tetrahedron Letters, 34, 1639-1639 (1993)
Takeshi Uemura et al.
The Journal of organic chemistry, 70(21), 8631-8634 (2005-10-08)
The addition of arylboronic acids 1 to azodicarboxylates 2 in the presence of a catalytic amount of a copper salt under mild reaction conditions gives aryl-substituted hydrazines 3 in high yields. The reaction is tolerant of a wide variety of
E A Bump et al.
International journal of radiation oncology, biology, physics, 29(2), 249-253 (1994-05-15)
To determine whether biological effects of radiation, such as apoptosis, that differ from classical clonogenic cell killing, can be modified with agents that would not be expected to modify classical clonogenic cell killing. This would expand the range of potential
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