227307

Natriumtriethylborhydrid -Lösung

1.0 M in toluene

• Synonym(e): Sodium triethylborate, Sodium triethylhydridoborate, Sodium triethylhydroborate
• Lineare Formel: (C₂H₅)₃NaBH
• CAS-Nummer: 17979-81-6
• Molekulargewicht: 121.99
• Beilstein: 4151241
• MDL-Nummer: MFCD00011704
• UNSPSC-Code: 12352000
• PubChem Substanz-ID: 24853623
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Qualitätsniveau: 100
• Eignung der Reaktion: reagent type: reductant
• Konzentration: 1.0 M in toluene
• Dichte: 0.866 g/mL at 25 °C
• SMILES String: [Na+].[H][B-](CC)(CC)CC
• InChI: 1S/C6H16B.Na/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1
• InChIKey: YDTZLEUIYNMRLQ-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Preparation of alcohols by hydrogenation of ketones catalyzed by an iron pincer complex
• Preparation of alkali metal boron monohydride complexes
• Coordinative substitution reactions
• Ligand exchange reactions

• Hydridic reagent

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H261,H304,H314,H336,H361d,H373,H412
• P-Sätze: P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 44.6 °F - closed cup
• Flammpunkt (°C): 7 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter