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Merck

201146

Sigma-Aldrich

Lithiumhexafluorophosphat

98%

Synonym(e):

Lithiumphosphorfluorid

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About This Item

Lineare Formel:
LiPF6
CAS-Nummer:
Molekulargewicht:
151.91
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

Qualität

for analytical purposes

Assay

98%

Form

powder

mp (Schmelzpunkt)

200 °C (dec.) (lit.)

Löslichkeit

H2O: slightly soluble(lit.)

Dichte

1.5 g/mL (lit.)

SMILES String

[Li+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChIKey

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Allgemeine Beschreibung

Lithium hexafluorophosphate is a white to off-white color compound that comes in powder or chunk form and is widely used in electrochemical applications, particularly in lithium-ion batteries.

Anwendung

The main use of LiPF6 is as an electrolyte salt in lithium-ion batteries. It plays a crucial role in the electrolyte solution, enhancing overall ionic conductivity and electrochemical stability. This makes it vital for R&D applications in high-performance batteries in consumer electronics, electric vehicles, and energy storage systems. LiPF6 assists in forming a stable SEI layer on the anode, which is essential for the durability and reliability of lithium-ion batteries. This layer helps prevent degradation and improves battery safety. LiPF6 is useful in R&D applications for the production of thin films and coatings for various electronic and optical applications, enhancing the performance and stability of these materials. It can be used as a catalyst or catalyst component in various organic synthesis reactions, particularly those requiring a strong Lewis acid.

Leistungsmerkmale und Vorteile

  • It can form suitable SEI membranes in electrodes, especially in the cathode
  • It can implement passivation for anode current collectors to prevent their dissolution
  • Wide windows of electrical stability
  • Excellent solubility and high conductivity in various solvents
  • Environment-friendly

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

Zielorgane

Bone,Teeth

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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M D S Lekgoathi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 153, 651-654 (2015-10-11)
The structure of LiPF6 has been probed using Raman scattering as well as pXRD and the results are compared and contrasted. The conventional Bragg angle scattering pXRD determines that dry LiPF6 crystallizes in a trigonal structure (Space Group R-3 (148))
Kewei Liu et al.
ACS nano, 9(6), 6041-6049 (2015-06-06)
The two-dimensional single-layer and few-layered graphene exhibit many attractive properties such as large specific surface area and high charge carrier mobility. However, graphene sheets tend to stack together and form aggregates, which do not possess the desirable properties associated with
Shijia Zhao et al.
Nanoscale, 7(5), 1984-1993 (2014-12-30)
Hydrogenated carbon nanomaterials exhibit many advantages in both mechanical and electrochemical properties, and thus have a wide range of potential applications. However, methods to control the hydrogenation and the effect of hydrogenation on the microstructure and properties of the produced
Jiangfeng Qian et al.
Nature communications, 6, 6362-6362 (2015-02-24)
Lithium metal is an ideal battery anode. However, dendrite growth and limited Coulombic efficiency during cycling have prevented its practical application in rechargeable batteries. Herein, we report that the use of highly concentrated electrolytes composed of ether solvents and the

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