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175064
Nitrosyltetrafluorborat
95%
Synonym(e):
Nitrosoniumtetrafluoroborat
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About This Item
Lineare Formel:
NOBF4
CAS-Nummer:
Molekulargewicht:
116.81
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352101
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
95%
Eignung der Reaktion
reagent type: oxidant
Lagertemp.
2-8°C
SMILES String
N#[O+].F[B-](F)(F)F
InChI
1S/BF4.NO/c2-1(3,4)5;1-2/q-1;+1
InChIKey
KGCNVGDHOSFKFT-UHFFFAOYSA-N
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Anwendung
Nitrosyl tetrafluoroborate is an efficient nitrosating and diazotizing agent. It reacts with alcohols and secondary amines to yield alkyl nitrites and nitrosamines, respectively. It reacts with primary amines to yield diazonium tetrafluoroborates. NOBF4 is also a mild oxidant and commonly used for single electron transfer oxidation.
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Skin Corr. 1B
Lagerklassenschlüssel
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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S Mohr et al.
The Journal of biological chemistry, 274(14), 9427-9430 (1999-03-27)
S-Nitrosylation of protein thiol groups by nitric oxide (NO) is a widely recognized protein modification. In this study we show that nitrosonium tetrafluoroborate (BF4NO), a NO+ donor, modified the thiol groups of glyceraldehyde-3-phosphate dehydrogenase (GAPDH) by S-nitrosylation and caused enzyme
J Li et al.
Biochemical and biophysical research communications, 240(2), 419-424 (1997-12-06)
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Guha, Samit et al.
Journal of the American Chemical Society, 133(39), 15256-15259 (2011)
S Mohr et al.
FEBS letters, 348(3), 223-227 (1994-07-18)
Previous studies have suggested that glyceraldehyde-3-phosphate dehydrogenase (GAPDH) undergoes covalent modification of an active site thiol by a NO.-induced [32P]NAD(+)-dependent mechanism. However, the efficacy of GAPDH modification induced by various NO donors was found to be independent of spontaneous rates
C Würth et al.
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The rational design of brighter upconversion nanoparticles (UCNPs) requires a better understanding of the radiationless deactivation pathways in these materials. Here, we demonstrate the potential of excitation power density (P)-dependent studies of upconversion (UC) luminescence intensities, slope factors, and absolute
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