Skip to Content
Merck
All Photos(3)

Key Documents

View All Documentation

108189

Sigma-Aldrich

Tris(hydroxymethyl)nitromethane

98%

Synonym(s):

2-Hydroxymethyl-2-nitro-1,3-propanediol

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
NO2C(CH2OH)3
CAS Number:
126-11-4
Molecular Weight:
151.12
Beilstein:
1768985
EC Number:
204-769-5
MDL number:
MFCD00007395
UNSPSC Code:
12352100
PubChem Substance ID:
24846654
NACRES:
NA.22

Assay

98%

form

solid

mp

160 °C (dec.) (lit.)

solubility

H2O: soluble 220g/100ml at 20 °C
alcohols: freely soluble
benzene: very slightly soluble
hydrocarbons: very slightly soluble

functional group

amine
hydroxyl
nitro

SMILES string

OCC(CO)(CO)[N+]([O-])=O

InChI

1S/C4H9NO5/c6-1-4(2-7,3-8)5(9)10/h6-8H,1-3H2

InChI key

OLQJQHSAWMFDJE-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Tris(hydroxymethyl)nitromethane undergoes crosslinking with hexamethylene diisocyanate to form monolithic energetic gels. It is an effective hardener for variety of tannin-based adhesives.

Preparation Note

220 g of Tris(hydroxymethyl)nitromethane dissolves in 100 ml of water at 20°C.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H412

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCR7146
MKCP1920
MKCP1394
MKCM5641
MKCL1139

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

M H Robertson et al.
Archives of dermatology, 118(12), 997-1002 (1982-12-01)
Two machinists were seen whose chronic hand dermatitis was explained by allergic sensitivity to a biocide, Tris Nitro (2-[hydroxymethyl]-2-nitro-1,3-propanediol), which was added to their metalworking fluids (cutting oils) to prevent rancidity. The cause of the men's difficulty was first suspected
A no-aldehyde emission hardener for tannin-based wood adhesives for exterior panels
Trosa A and Pizzi A.
European Journal of Wood and Wood Products, 59(4), 266-271 (2001)
Nanostructured Energetic Composites of CL-20 and Binders Synthesized by Sol Gel Methods.
Li J and Brill TB.
Propellants, Explosives, Pyrotechnics, 31(1), 61-69 (2006)
Bacterial inhibitors for cutting oil.
H O WHEELER et al.
Applied microbiology, 4(3), 122-126 (1956-05-01)
Ross C Beier et al.
Journal of food science, 84(6), 1501-1512 (2019-05-23)
Susceptibility profiles were determined for 111 Campylobacter coli strains obtained in 1998 to 1999 and 2015 from market age pigs and pork chops against 22 disinfectants and 9 antimicrobials. Resistance to tetracycline (TET) was observed in 44.4% of 1998 to
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service