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Merck
모든 사진(1)

문서

438081

Sigma-Aldrich

Phosphoric acid

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ACS reagent, ≥85 wt. % in H2O

동의어(들):

Orthophosphoric acid

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About This Item

Linear Formula:
H3PO4
CAS Number:
Molecular Weight:
98.00
Beilstein:
1921286
EC Number:
MDL number:
UNSPSC 코드:
12352106
PubChem Substance ID:
NACRES:
NA.21

Grade

ACS reagent

vapor density

3.4 (vs air)

vapor pressure

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

분석

≥85% (with NaOH, titration)

형태

liquid

환경친화적 대안 제품 특성

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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농도

≥85 wt. % in H2O

기술

NMR: suitable

불순물

Reducing substances, passes test
≤0.001% volatile acids (as CH3COOH)

색상

APHA: ≤10

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

음이온 미량물

chloride (Cl-): ≤3 ppm
nitrate (NO3-): ≤5 ppm
sulfate (SO42-): ≤0.003%

양이온 미량물

As: ≤1 ppm
Ca: ≤0.002%
Fe: ≤0.003%
K: ≤0.005%
Mg: ≤0.02%
Mn: ≤0.5 ppm
Na: ≤0.025%
Sb: ≤0.002%
heavy metals: ≤0.001% (by ICP)

환경친화적 대안 카테고리

SMILES string

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

유전자 정보

human ... SRC(6714)

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일반 설명

Phosphoric acid (H3PO4), also known as orthophosphoric acid, is an inorganic acid. It has a wide range of industrial applications such as an intermediate to produce animal feedstock, to prepare stock solutions for workup procedures and to treat the metal surfaces for better adhesion of paint and resin coatings. In the food industry it is used as a preservative, an acidulant and flavor enhancer.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

애플리케이션

Phosphoric acid may be employed as standard for the determination of phosphorus-31 nuclear magnetic resonance (31P NMR) chemical shifts of the common phospholipids. It may be employed in the following studies:
  • As external standard for the analysis of lipid composition of human white matter by 31P NMR spectroscopy.
  • As external standard during the acid-labile phosphorylation of histone H4 by 31P NMR spectroscopy.
  • As reference standard to investigate the surface species present on silica/alumina-supported sodium phosphates by pre- and postreaction MAS31P-NMR and FTIR spectroscopies.
  • As catalyst in the vapor-phase Fries rearrangement of phenylacetate at 623K over a series of surface modified and unmodified ZSM-5.
  • As an eco-friendly reagent for the removal of protecting groups like tert-butyl carbamates, tert-butyl esters and tert-butyl ethers.

기타 정보

Concentrated phosphoric acid is approx. 85% H3PO4 (aqueous).

픽토그램

CorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 1

1 of 1

Aqueous phosphoric acid as a mild reagent for deprotection of tert-butyl carbamates, esters, and ethers.
Li B, et al.
The Journal of Organic Chemistry, 71(24), 9045-9050 (2006)
Myers RL.
The 100 Most Important Chemical Compounds: A Reference Guide, 220-220 (2007)
A simple method of increasing the adhesion of acrylic filling materials to enamel surfaces.
Buonocore MG.
Journal of Dental Research, 34(6), 849-853 (1955)
FTIR and 31 P-NMR spectroscopic analyses of surface species in phosphate-catalyzed lactic acid conversion.
Gunter GC, et al.
J. Catal., 164(1), 207-219 (1996)
Internal versus external surface active sites in ZSM-5 zeolite: Part 1. Fries rearrangement catalyzed by modified and unmodified H3PO4/ZSM-5.
Ghiaci M, et al.
Applied Catalysis A: General, 298, 32-39 (2006)

프로토콜

To measure alcohol dehydrogenase activity, this assay uses β-nicotinamide adenine dinucleotide phosphate and a continuous spectrophotometric rate determination at 340 nm.

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