추천 제품
애플리케이션
Mediates monoprotection of symmetrical diols with alkyl halides in good to excellent yield.[1]
Silver(I) oxide may be used to mediate the following processes:
- Selective monoalkylation of symmetric diols in the presence of alkyl halide.[2]
- Palladium catalyzed cross-coupling of aryl- and alkenylsilanols with organic halides.[3]
- Palladium-catalyzed reaction of aryl and alkenyl halides with terminal alkynes to form arylated or alkenylated alkynes, respectively.[4]
법적 정보
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신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1
Storage Class Code
5.1A - Strongly oxidizing hazardous materials
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
시험 성적서(COA)
이미 열람한 고객
Highly selective silver (I) oxide mediated monoprotection of symmetrical diols
Tetrahedron Letters, 38(34), 5945-5948 (1997)
A New Transformation of Silanols. Palladium-Catalyzed Cross-Coupling with Organic Halides in the Presence of Silver (I) Oxide
Organic Letters, 1(2), 299-302 (1999)
Concise Encyclopedia Chemistry, 90-90 (1994)
Non-Sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver (I) oxide or tetrabutylammonium fluoride.
Organic Letters, 2(19), 2935-2937 (2000)
Organic letters, 4(14), 2329-2332 (2002-07-06)
[reaction: see text] The reaction of symmetrical diols and oligo(ethylene glycol)s with a stoichiometric amount of p-toluenesulfonyl chloride in the presence of silver(I) oxide and a catalytic amount of potassium iodide led selectively to the monotosylate derivatives in high yields.
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