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Merck
모든 사진(1)

문서

90520

Sigma-Aldrich

Triethyloxonium tetrafluoroborate

≥97.0% (T)

동의어(들):

Et3OBF4, Meerwein′s reagent, Triethyloxonium fluoroborate

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About This Item

Linear Formula:
(C2H5)3O(BF4)
CAS Number:
Molecular Weight:
189.99
Beilstein:
3598090
MDL number:
UNSPSC 코드:
12352001
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

≥97.0% (T)

형태

crystals

포함

1-3% ether as stabilizer

solubility

methylene chloride: 20 mg/mL, clear, colorless

저장 온도

2-8°C

SMILES string

F[B-](F)(F)F.CC[O+](CC)CC

InChI

1S/C6H15O.BF4/c1-4-7(5-2)6-3;2-1(3,4)5/h4-6H2,1-3H3;/q+1;-1

InChI key

IYDQMLLDOVRSJJ-UHFFFAOYSA-N

애플리케이션

Triethyloxonium tetrafluoroborate can be used:
  • To prepare amino esters by reacting with lactams followed by hydrolysis.
  • In the preparation of substituted imidazolines from aziridines and nitriles via [3+2]-cycloaddition reaction.
  • For the N-alkylation of a series of N-arylsulfonyl-α-amino acid methyl esters having variable substituents at 4th position of the sulfonamide aromatic ring.

기타 정보

Powerful ethylating agent; Esterification of acids; Modifies carboxyl residues in proteins

픽토그램

Corrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

보충제 위험성

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Synthesis of substituted imidazolines via [3+ 2]-cycloaddition of aziridines with nitriles
Prasad BAB, et al.
Tetrahedron Letters, 45(6), 1137-1141 (2004)
M.J. Diem et al.
The Journal of Organic Chemistry, 42, 1801-1801 (1977)
The identification of aspartic acid residue 52 as being critical to lysozyme activity.
S M Parsons et al.
Biochemistry, 8(10), 4199-4205 (1969-10-01)
D.J. Raber et al.
The Journal of Organic Chemistry, 44, 1149-1149 (1979)
H. Meerwein et al.
Angewandte Chemie (International Edition in English), 72, 927-927 (1960)

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