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Merck
모든 사진(1)

문서

164283

Sigma-Aldrich

Methyl trifluoromethanesulfonate

≥98%

동의어(들):

Methyl triflate

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About This Item

Linear Formula:
CF3SO2OCH3
CAS Number:
Molecular Weight:
164.10
Beilstein:
774772
EC Number:
MDL number:
UNSPSC 코드:
12352108
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

≥98%

형태

liquid

refractive index

n20/D 1.326 (lit.)

bp

94-99 °C (lit.)

density

1.45 g/mL at 25 °C (lit.)

저장 온도

2-8°C

SMILES string

COS(=O)(=O)C(F)(F)F

InChI

1S/C2H3F3O3S/c1-8-9(6,7)2(3,4)5/h1H3

InChI key

OIRDBPQYVWXNSJ-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Methyl trifluoromethanesulfonate is a strong methylating reagent, commonly used for the pre-methylation of polysaccharides under mild basic conditions.

애플리케이션

Methyl trifluoromethanesulfonate can be used as a methylation reagent:
  • In the determination of polysulfides, zerovalent sulfur in sulfide-rich water wells, and polysulfide species in electrolyte of a lithium–sulfur battery using chromatography-based techniques.
  • In reactions with potassium enolates.
  • For the conversion of amines to methyl ammonium triflates.

픽토그램

FlameSkull and crossbonesCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

100.4 °F - closed cup

Flash Point (°C)

38 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


시험 성적서(COA)

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Ring Expansions of 2-Alkenylazetidinium Salts-a New Route to Pyrrolidines and Azepanes
Couty F, et al.
European Journal of Organic Chemistry, 2006(18), 4214-4223 (2006)
Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium?Sulfur Battery using HPLC ESI/MS with One?Step Derivatization
Zheng D, et al.
Advanced Energy Materials, 5(16) (2015)
Oliver Schuster et al.
Inorganic chemistry, 45(20), 7997-7999 (2006-09-27)
Two cationic carbene complexes with no heteroatom in the ring containing the carbene carbon, trans-bromo(2-methyl-2,6-dihydroisoquinolin-6-ylidene)bis(triphenylphosphine)palladium(II) triflate (3) and trans-chloro(1,2-dimethyl-1,7-dihydroquinolin-7-ylidene)bis(triphenylphosphine)palladium(II) triflate (4), were synthesized by oxidative substitution of Pd(PPh3)4 with N-methylated 6-bromoisoquinolinium and 7-chloro-2-methylquinolinium cations, respectively. Compound 3 was also prepared
Convenient gas phase bromination of [11C]methane and production of [11C]methyl triflate.
B H Mock et al.
Nuclear medicine and biology, 26(4), 467-471 (1999-06-26)
Alkylation of enolates with triflates
Bates RB and Taylor SR
The Journal of Organic Chemistry, 58(16), 4469-4470 (1993)

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