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Merck
모든 사진(2)

주요 문서

128465

Sigma-Aldrich

Glyoxal solution

40 wt. % in H2O

동의어(들):

Ethanedial, Oxalaldehyde

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크기 선택

5 G
₩91,655
100 G
₩114,898
1 KG
₩129,108
3 KG
₩224,721
22 KG
₩1,498,952

₩91,655


예상 입고일2025년 1월 31일세부사항


벌크 견적 요청

크기 선택

보기 변경
5 G
₩91,655
100 G
₩114,898
1 KG
₩129,108
3 KG
₩224,721
22 KG
₩1,498,952

About This Item

Linear Formula:
OHCCHO
CAS Number:
Molecular Weight:
58.04
Beilstein:
1732463
MDL number:
UNSPSC 코드:
12352114
PubChem Substance ID:
NACRES:
NA.21
양식:
liquid

₩91,655


예상 입고일2025년 1월 31일세부사항


벌크 견적 요청

vapor density

>1 (vs air)

Quality Level

vapor pressure

18 mmHg ( 20 °C)

양식

liquid

autoignition temp.

545 °F

농도

40 wt. % in H2O

refractive index

n20/D 1.4087

solubility

water: soluble(lit.)

density

1.265 g/mL at 25 °C

작용기

aldehyde

SMILES string

[H]C(=O)C([H])=O

InChI

1S/C2H2O2/c3-1-2-4/h1-2H

InChI key

LEQAOMBKQFMDFZ-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

The product is 40wt.% solution of glyoxal in water. Glyoxal is a linear aliphatic dialdehyde containing two aldehyde groups.[1] It participates in the synthesis of glyoxylic acid. It is highly reactive in nature. It can be prepared by oxidizing ethanol or acetaldehyde with nitric acid. It is widely employed in textile and paper industry.[2]

애플리케이션

Glyoxal solution has been used as a crosslinking agent during the synthesis of DNA-containing nanoparticles in a study.[3] It has been used as derivatizing reagent, in the precolumn fluorescence derivatization of N-terminal tryptophan containing peptides which can be separated via high performance liquid chromatography.[4] It may also be used in the synthesis of glyoxal bis(4-phenyl-3-thiosemicarbazones)solution, which can be used in the spectrophotometric determination of palladium in catalysts.[5]

기타 정보

This form of glyoxal is composed of 3 moles of glyoxal and 2 moles of water in a relatively stable configuration.

주의사항

May precipitate on storage; redissolve at 50-60 °C.

픽토그램

Health hazardCorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Dam. 1 - Muta. 2 - Skin Corr. 1 - Skin Sens. 1 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

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이 제품을 이미 가지고 계십니까?

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문서 라이브러리 방문

"High-performance liquid chromatography of N-terminal tryptophan-containing peptides with precolumn fluorescence derivatization with glyoxal"
Kai M, et al.
Journal of Chromatography A, 653(2), 235-240 (1993)
Eagleson M.
Concise Encyclopedia Chemistry, 465-465 (1994)
Eagleson M.
Concise Encyclopedia Chemistry, 312-312 (1994)
Spectrophotometric determination of palladium in catalysts with glyoxal bis (4-phenyl-3-thiosemicarbazone)
Asuero A, et al.
Analyst, 111(7), 747-755 (1986)
Jing Xu et al.
Journal of visualized experiments : JoVE, (59)(59), e3612-e3612 (2012-01-11)
More than 32,000 patients are diagnosed with pancreatic cancer in the United States per year and the disease is associated with very high mortality (1). Urgent need exists to develop novel clinically-translatable therapeutic strategies that can improve on the dismal

질문

1–7 / 7 질문  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What are the storage conditions of the 100G package size supplied in a single 125 mL bottle?

    1 답변
    1. This product may be stored at room temperature. Note that any precipitates that may appear upon long term storage may be dissolved by warming the material to 50-60 °C.

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  4. Would the Glyoxal in this solution be stable if added to an Ethanol water mixture (50-75%) and stored for a prolonged period of time?

    1 답변
    1. Stability/shelf life information for Product 128465 dissolved in ethanol is unavailable.

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  5. Hello, for the Glyoxal solution 40% (128465) it is described "This form of glyoxal is composed of 3 moles of glyoxal and 2 moles of water..." What does it mean? If glyoxal solution is 40% the molar ratio glyoxal:water should be 1:5. Best regards Maja

    1 답변
    1. Product 128465 concentration is ~40% wt % in H2O which is 40 g of solid divided by 100 g of water and ~8.8 M (Moles/L). Please be mindful that the moles represent a different unit of measurement than weight percent and molarity and their ratios will vary as moles do not represent the concentration of the solution. A mole is defined as the amount of a substance that contains exactly 6.0221023 elementary entities of the given substance. 2 moles of water molecules are needed to stabilize 3 moles of glyoxal molecules as pure glyoxal is not commonly encountered since solid glyoxal around room temperature is a yellow liquid that gives off a green vapor. Commercially, it is usually handled as a 40% aqueous solution (density near 1.24 g/mL).

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  6. Hello, Is there a straightforward way to get this solution of glyoxal into the gas phase so that it can be introduced into an atmospheric simulation chamber for the purpose of testing developmental gas sensing systems? Kind regards, Eibhlín

    1 답변
    1. Information regarding the vapor pressure of the glyoxal cannot be provided. The conditions required for volatilization are unknown. It may be possible to begin by making an aerosol, using a bottle-type sprayer, see Product Z126306-1SET for example:
      https://www.sigmaaldrich.com/product/aldrich/z126306

      To further discuss, we kindly ask you to navigate to the link https://www.sigmaaldrich.com/techservice and click on "Product Technical Inquires" under the Products Section with all the required information so that a member of our Technical Service team can reach out to you to assist further. Thank you.

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  7. Hi! We want to buy 100g, but we were wondering if all the volume comes togheter in a big vial, or is it individual vials? thanks!

    1 답변
    1. The 100G package size is supplied in a single 125 mL bottle.

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