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Merck
모든 사진(1)

주요 문서

W387509

Sigma-Aldrich

Dimethyl sulfoxide

≥99%

동의어(들):

DMSO

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About This Item

Linear Formula:
(CH3)2SO
CAS Number:
Molecular Weight:
78.13
FEMA Number:
3875
Beilstein:
506008
EC Number:
MDL number:
UNSPSC 코드:
12191502
PubChem Substance ID:
플래비스(Flavis) 번호:
12.175

생물학적 소스

synthetic

Grade

Halal

Agency

meets purity specifications of JECFA

vapor density

2.7 (vs air)

vapor pressure

0.42 mmHg ( 20 °C)

분석

≥99%

autoignition temp.

573 °F

유통기한

Expiration date period - 5 years

expl. lim.

42 %, 63 °F

색상

colorless

refractive index

n20/D 1.479 (lit.)

bp

189 °C (lit.)
189 °C

mp

16-19 °C (lit.)

solubility

water: miscible

density

1.10 g/mL (lit.)

응용 분야

flavors and fragrances

문건

see Safety & Documentation for available documents

식품 알레르기항원

no known allergens

감각 수용성의

butter; sulfurous

SMILES string

CS(C)=O

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3

InChI key

IAZDPXIOMUYVGZ-UHFFFAOYSA-N

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일반 설명

Dimethyl sulfoxide (DMSO) is a hygroscopic, high polarity amphiphilic solvent with an ability to dissolve many compounds.[1] Cytotoxic study of DMSO on the pulp tissue repair-related activity of odontoblast-like cells showed it produced minor effects.[2] Along with phosphorus pentaoxide it participates in the oxidation of carbohydrates to afford aldosuloses and aldosiduloses.[3] DMSO participates in the oxidation of some partially-acetylated carbohydrates followed by elimination to afford unsaturated, derivatives.[4] Solubility of amylose and amylopectin in DMSO has been evaluated.[5]

애플리케이션

DMSO has been used to prepare the DMSO-phosphate buffer solution, which was used to dissolve the selective ETB (ET = endothelin) receptor antagonist in a study.[6] It has been used for the preparation of nysatin solution.[7]
Dimethyl sulfoxide may be used in the synthesis of the following:
  • α, β−Unsaturated carbonyl sugar derivatives.[8]
  • Conversion of secondary bromides or olefins to bromohydrin.[9]
  • Synthesis of α-hydroxycarbonyls from corresponding ketones.[10]

주의사항

Supercools easily and remelts slowly at room temperature. Solidified product can be re-liquified by warming to room temperature without detriment to the product.

관련 제품

제품 번호
설명
가격

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point (°F)

188.6 °F - closed cup

Flash Point (°C)

87 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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문서 라이브러리 방문

이미 열람한 고객

I2-or NBS-Catalyzed Highly Efficient α-Hydroxylation of Ketones with Dimethyl Sulfoxide.
Liang YF, et al.
Organic Letters, 17(4), 876-879 (2015)
From simple organobromides or olefins to highly value-added bromohydrins: a versatile performance of dimethyl sulfoxide.
Song S, et al.
Green Chemistry, 17(5), 2727-2731 (2015)
Synthesis of α, β-unsaturated, carbonyl sugar derivatives by methyl sulfoxide oxidation and elimination.
Mackie DM and Perlin AS.
Carbohydrate Research, 24(1), 67-85 (1972)
Solubility behavior of granular corn starches in methyl sulfoxide (DMSO) as measured by high performance size exclusion chromatography.
Jackson DS.
Starch/Staerke, 43(11), 422-427 (1991)
David Jarriault et al.
Journal of visualized experiments : JoVE, (101)(101), e52652-e52652 (2015-08-15)
Analyzing the physiological responses of olfactory sensory neurons (OSN) when stimulated with specific ligands is critical to understand the basis of olfactory-driven behaviors and their modulation. These coding properties depend heavily on the initial interaction between odor molecules and the

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