B92001

4-tert-Butylcyclohexanol, mixture of cis and trans

98%

• Linear Formula: (CH₃)₃CC₆H₁₀OH
• CAS Number: 98-52-2
• Molecular Weight: 156.27
• Beilstein: 1902277
• EC Number: 202-676-4
• MDL number: MFCD00001473
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24892127
• NACRES: NA.22

속성

• 분석: 98%
• 형태: powder
• bp: 110-115 °C/15 mmHg (lit.)
• mp: 62-70 °C (lit.)
• SMILES string: CC(C)(C)C1CCC(O)CC1
• InChI: 1S/C10H20O/c1-10(2,3)8-4-6-9(11)7-5-8/h8-9,11H,4-7H2,1-3H3
• InChI key: CCOQPGVQAWPUPE-UHFFFAOYSA-N

설명

애플리케이션

4-tert-Butylcyclohexanol (mixture of cis and trans) can be used as a reactant to synthesize tris(4,4′-di-tert-butyl-2,2′-bipyridine)(trans-4-tert-butylcyclohexanolato)deca-μ-oxido-heptaoxidoheptavanadium oxide cluster complex by reacting with [V₈O₂₀(C₁₈H₂₄N₂)₄]. It can also be used as a reactant in competitive Oppenauer oxidation experiments in the presence of zeolite BEA as a stereoselective catalyst. Only cis-isomer is selectively converted to the corresponding ketone, whereas trans-isomer remains unchanged.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H319
• 예방조치 성명서: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point (°F): 221.0 °F - closed cup
• Flash Point (°C): 105 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)