ALD00594

2-Hydroxynicotinaldehyde

97%

• 동의어(들): 2-Hydroxy-pyridine-3-carbaldehyde, TDG4
• 실험식(Hill 표기법): C₆H₅NO₂
• CAS Number: 36404-89-4
• Molecular Weight: 123.11
• MDL number: MFCD09909918
• UNSPSC 코드: 12352200
• NACRES: NA.22

속성

• 분석: 97%
• 형태: powder or crystals
• 반응 적합성: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• mp: 223 °C
• 작용기: aldehyde
• 저장 온도: 2-8°C
• InChI: 1S/C6H5NO2/c8-4-5-2-1-3-7-6(5)9/h1-4H,(H,7,9)
• InChI key: DNTYEVWEOFZXFE-UHFFFAOYSA-N

설명

애플리케이션

This reagent was used as a catalytic transient directing group by Jin-Quan Yu′s lab for Pd(II)-catalyzed γ-C(sp³)-H arylation to couple free primary amines with aryl iodides. Reactions included Pd(OAc)₂ 683124 and low catalyst and directing group loading.

문헌인용

Pd-Catalyzed γ-C(sp³)-H Arylation of Free Amines Using a Transient Directing Group

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable