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Merck
모든 사진(2)

주요 문서

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802948

Sigma-Aldrich

(dppf)Ni(o-tolyl)Cl

동의어(들):

Buchwald Ni Catalyst

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크기 선택

250 MG
₩112,767
1 G
₩368,344

₩112,767

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청
모든 사진(2)

크기 선택

보기 변경
250 MG
₩112,767
1 G
₩368,344

About This Item

실험식(Hill 표기법):
C41H35ClFeNiP2
CAS Number:
1501945-23-8
Molecular Weight:
739.66
MDL number:
MFCD28411349
UNSPSC 코드:
12161600
PubChem Substance ID:
329768766
NACRES:
NA.22

₩112,767

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청

분석

95%

Quality Level

100

양식

powder

반응 적합성

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

173 °C

저장 온도

2-8°C

SMILES string

CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe]

InChI

1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1

InChI key

LGLPATFHWYLMCO-UHFFFAOYSA-M

관련 카테고리

일반 설명

(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.[1]

픽토그램

Health hazardEnvironment
GHS08,GHS09

신호어

Danger

유해 및 위험 성명서

H317,H334,H341,H350,H360,H372,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 2

1 of 2

Tetrakis(triphenylphosphine)nickel(0) Ni 4-7 % (approx.)

Sigma-Aldrich

244996

Tetrakis(triphenylphosphine)nickel(0)

Cyclopentyl methyl ether inhibitor-free, anhydrous, ≥99.9%

Sigma-Aldrich

791962

Cyclopentyl methyl ether

Nathaniel H Park et al.
Organic letters, 16(1), 220-223 (2013-11-29)
A new air-stable nickel precatalyst for C-N cross-coupling is reported. The developed catalyst system displays a greatly improved substrate scope for C-N bond formation to include both a wide range of aryl and heteroaryl electrophiles and aryl, heteroaryl, and alkylamines.

문서

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

질문

  1. Is it water soluble?

    1 답변

    1. This product is not tested for solubility. A literature search does not yield conclusive information regarding water solubility. Further experimentation would be necessary to determine this parameter. Please see the links below to review articles that may be helpful.

      Well-defined nickel and palladium precatalysts for cross-coupling
      https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5637737/

      Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations
      https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540912/

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