모든 사진(1)
About This Item
실험식(Hill 표기법):
C12H13NO
CAS Number:
Molecular Weight:
187.24
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
NACRES:
NA.22
추천 제품
분석
97%
양식
liquid
refractive index
n20/D 1.644
density
1.134 g/mL at 25 °C
저장 온도
2-8°C
SMILES string
CC(C)c1cccc2ccc[n+]([O-])c12
InChI
1S/C12H13NO/c1-9(2)11-7-3-5-10-6-4-8-13(14)12(10)11/h3-9H,1-2H3
InChI key
LYLSTLGFFOQSKE-UHFFFAOYSA-N
애플리케이션
8-Isopropylquinoline N-oxide can be used as a reagent:
- In the oxidative cyclization of diynes in the presence of gold catalyst.[1]
- For the preparation of pyrrolo[3,4-c]quinolin-1-ones by asymmetric alkyne oxidation of chiral N-propargyl ynamides in the presence of a copper catalyst.[2]
- In the synthesis of 8-(1-methylethyl)-2-[(4-methylphenyl)sulfonyl]- quinoline by deoxygenative and selective sulfonylation with sodium p-toluenesulfinate using iodine/TBHP as a catalyst.[3]
Storage Class Code
12 - Non Combustible Liquids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
Recent advances in catalytic asymmetric intermolecular oxidation of alkynes
Shen W-B and Tang X-T
Organic & Biomolecular Chemistry, 17(30), 7106-7113 (2019)
Iodine/TBHP-Promoted One-Pot Deoxygenation and Direct 2-Sulfonylation of Quinoline N-Oxides with Sodium Sulfinates: Facile and Regioselective Synthesis of 2-Sulfonylquinolines
Sumunnee L, et al.
European Journal of Organic Chemistry, 2017(5), 1025-1032 (2017)
Pascal Nösel et al.
Journal of the American Chemical Society, 135(41), 15662-15666 (2013-09-21)
In the presence of a gold catalyst an unprecedented oxidative cyclization of diynes takes place. The reaction cascade is initiated by an oxygen transfer from a N-oxide onto a gold-activated alkyne. The formed α-oxo carbene is transferred across the second
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