The recommended storage temperature for this item is 2-8°C for a 70 wt.% tert-Butyl hydroperoxide solution in water. Storage has not been evaluated after dilution in DMEM or MEM. Solutions at more dilute concentrations can be prepared as needed. A cell viability and an apoptosis assay would need to be performed on a fresh versus stored sample with varying concentrations of tert-butyl hydroperoxide to determine if potency is altered.
458139
tert-Butyl hydroperoxide solution
tert-Butyl hydroperoxide solution
70 wt. % in H2O
동의어(들):
TBHP, 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane
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모든 사진(1)
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25 ML
₩78,257
100 ML
₩92,873
1 L
₩136,924
About This Item
Linear Formula:
(CH3)3COOH
CAS Number:
Molecular Weight:
90.12
Beilstein:
1098280
MDL number:
UNSPSC 코드:
12162002
PubChem Substance ID:
NACRES:
NA.23
추천 제품
양식
liquid
Quality Level
반응 적합성
reaction type: C-H Activation
reagent type: catalyst
reagent type: oxidant
농도
12.25-13.31% (active oxygen)
69.0-75.0% (Na2S2O3, titration)
70 wt. % in H2O
refractive index
n20/D 1.386
pH
4.3
bp
96.2 °C
density
0.93 g/mL at 25 °C
저장 온도
2-8°C
SMILES string
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
법적 정보
Product of Arkema Inc.
신호어
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
Flash Point (°F)
107.6 °F - closed cup
Flash Point (°C)
42 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Sci. Synth., 3, 91-131 (2004)
Inorgorganica Chimica Acta, 357, 2237-2244 (2004)
Hsin-Yi Chen et al.
Nanoscale research letters, 13(1), 123-123 (2018-04-26)
Reactive oxygen species (ROS) have crucial roles in cell signaling and homeostasis. Overproduction of ROS can induce oxidative damage to various biomolecules and cellular structures. Therefore, developing an approach capable of monitoring and quantifying ROS in living cells is significant
J. Catal., 224, 288-296 (2004)
Laura Parma et al.
Cells, 9(2) (2020-02-07)
Unstable atherosclerotic plaques frequently show plaque angiogenesis which increases the chance of rupture and thrombus formation leading to infarctions. Hypoxia plays a role in angiogenesis and inflammation, two processes involved in the pathogenesis of atherosclerosis. We aim to study the
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Would it alter the potency of the molecule if diluted in cell culture medium (typically MEM and DMEM) then kept at -20 degrees celsius?
1 답변-
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 답변-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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How can I determine the shelf life / expiration / retest date of this product?
1 답변-
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf도움이 되었습니까?
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What does "percent active oxygen" on the COA for product 458139 mean? Shouldn't the specified range (12.25%-12.61%) be higher?
1 답변-
Approximately 70% of product 458139 is tert-Butyl hydroperoxide, and about 35.6% of the tert-Butyl hydroperoxide is oxygen, which might suggest that the oxygen content in the solution is about 24.9%. However, only one of the two oxygen atoms is considered 'active', leading to an active oxygen specification of around 12.4%. This concept is related to the energy content and is used to specify the amount of peroxide present in the formulation.
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Is t-BHP also stable at lower concentrations (at 4°C) diluted in H2O, e.g. 1M ? Or would you recommend to always prepare fresh (pre-) dilutions when lower concentrations are needed? Thanks!
1 답변-
Stability studies of dilute solutions have not been performed. To assure optimum quality, it is recommended that further dilutions be prepared fresh and not stored.
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Could you share the molarity of 70% TBHP solution?
1 답변-
The concentration range for this product is 69.0 - 75.0%. With the density of 0.93 g/mL, at 70% the calculated molarity of the product is 7.224.
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