745499
Zinc trifluoroethanesulfinate
동의어(들):
Baran TFES Reagent, Baran Trifluoroethylation Reagent, Bis(((2,2,2-trifluoroethyl)sulfinyl)oxy)zinc, TFES
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모든 사진(2)
About This Item
실험식(Hill 표기법):
C4H4F6O4S2Zn
CAS Number:
Molecular Weight:
359.58
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22
추천 제품
![Zinc di[bis(trifluoromethylsulfonyl)imide] 95%](/deepweb/assets/sigmaaldrich/product/structures/336/073/952daadd-0a7c-4bec-bbaf-442a24c62161/640/952daadd-0a7c-4bec-bbaf-442a24c62161.png)
양식
solid
반응 적합성
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
mp
114-120 °C
작용기
fluoro
sulfinic acid
SMILES string
O=S(O[Zn]OS(CC(F)(F)F)=O)CC(F)(F)F
InChI
1S/2C2H3F3O2S.Zn/c2*3-2(4,5)1-8(6)7;/h2*1H2,(H,6,7);/q;;+2/p-2
InChI key
PUGHSSOALZPRJD-UHFFFAOYSA-L
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일반 설명
Zinc trifluoroethanesulfinate (TFES) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.[1]
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Learn More at the Professor and Product Portal of Professor Phil S. Baran.
결합
Frequently Asked Questions are available for this Product.
기타 정보
Previously sold under product number L511234
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified
문서
Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.
활성 필터
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.
