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Merck
모든 사진(3)

주요 문서

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701718

Sigma-Aldrich

2-Azaadamantane-N-oxyl

90%

동의어(들):

AZADO

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크기 선택

50 MG
₩277,806
250 MG
₩824,079

₩277,806

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청
모든 사진(3)

크기 선택

보기 변경
50 MG
₩277,806
250 MG
₩824,079

About This Item

실험식(Hill 표기법):
C9H14NO
CAS Number:
57625-08-8
Molecular Weight:
152.21
MDL number:
MFCD11656077
UNSPSC 코드:
12352000
PubChem Substance ID:
329762314
NACRES:
NA.22

₩277,806

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청

분석

90%

양식

powder

반응 적합성

reagent type: oxidant

mp

182-189 °C (D)

저장 온도

2-8°C

SMILES string

[O]N1[C@@H]2C[C@H]3C[C@@H](C2)C[C@@H]1C3

InChI

1S/C9H14NO/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2/t6-,7+,8-,9+

InChI key

BCJCJALHNXSXKE-SPJNRGJMSA-N

관련 카테고리

일반 설명

2-Azaadamantane-N-oxyl (AZADO), a stable nitroxyl radical, is widely employed as catalyst for the oxidation of alcohols.[1]

애플리케이션

2-Azaadamantane-N-oxyl (AZADO) may be employed in the following studies:
  • As catalyst for the oxidation of wood cellulose.[2]
  • As catalyst in the total synthesis of Yaku′amide A, a potential cytotoxin obtained from sponge Ceratopsion sp.[3]
  • As oxidant for the oxidation of (S)-glycidol.[4]

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
BCCL8449
BCCK9853
BCCG6141
BCCG6140
BCCF9336

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특정 버전이 필요한 경우 로트 번호나 배치 번호로 특정 인증서를 찾을 수 있습니다.

COA 검색

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Takefumi Kuranaga et al.
Journal of the American Chemical Society, 135(14), 5467-5474 (2013-03-19)
Here we report the first total synthesis and the complete stereochemical assignment of yaku'amide A. Yaku'amide A (1) was isolated from a sponge Ceratopsion sp. as an extremely potent cytotoxin. Its structure was determined except for the C4-stereochemistry in the
Masatoshi Shibuya et al.
Journal of the American Chemical Society, 128(26), 8412-8413 (2006-06-29)
Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl
Ming Zhang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(10), 3937-3941 (2015-01-22)
An increased supply of scarce or inaccessible natural products is essential for the development of more sophisticated pharmaceutical agents and biological tools, and thus the development of atom-economical, step-economical and scalable processes to access these natural products is in high
Takuya Isogai et al.
Biomacromolecules, 11(6), 1593-1599 (2010-05-18)
Curdlan, amylodextrin, and regenerated cellulose fiber were subjected to electromediated oxidation with a 4-acetamido-TEMPO catalyst in a buffer at pH 6.8 without NaClO or NaClO(2). More than 90% of the C6 primary hydroxyls of Curdlan and amylodextrin were converted to

질문

1–2 / 2 질문  

  1. What are the benefits of the organocatalyst 2-Azaadamantane-N-oxyl, Product 701718?

    1 답변

    1. AZADO (2-azaadamantane N-oxyl) can convert alcohols to their corresopnding carbonyl compounds more effectively than the traditional TEMPO reagent in sterically hindered environments.

      도움이 되었습니까?

  2. What is the Department of Transportation shipping information for this product?

    1 답변

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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