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146048

Sigma-Aldrich

2-Adamantanone

ReagentPlus®, 99%

동의어(들):

2-Oxoadamantane, Tricyclo[3.3.1.13,7]decanone (9CI)

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크기 선택

5 G
₩49,634
25 G
₩140,375
100 G
₩276,080

₩49,634

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청
모든 사진(3)

크기 선택

보기 변경
5 G
₩49,634
25 G
₩140,375
100 G
₩276,080

About This Item

실험식(Hill 표기법):
C10H14O
CAS Number:
700-58-3
Molecular Weight:
150.22
Beilstein:
1210235
EC Number:
211-847-2
MDL number:
MFCD00074737
UNSPSC 코드:
12352100
PubChem Substance ID:
24848757
NACRES:
NA.22

₩49,634

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청

Quality Level

100

제품 라인

ReagentPlus®

분석

99%

양식

solid

mp

256-258 °C (subl.) (lit.)

작용기

ketone

SMILES string

O=C1C2CC3CC(C2)CC1C3

InChI

1S/C10H14O/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2/t6-,7+,8-,9+

InChI key

IYKFYARMMIESOX-SPJNRGJMSA-N

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관련 카테고리

일반 설명

2-Adamantanone on deprotonation in the gas phase affords the corresponding β-enolate anion[1]. It reacts with 1,1-dilithio-1-sila-2,3,4,5-tetraphenylsilole to yield 5-silafulvene[2].

애플리케이션

2-Adamantanone was used in the synthesis of dispiro N-Boc-protected 1,2,4-trioxane[3] and (+/-)-1-(adamantan-2-yl)-2-propanamine[4].

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves

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시험 성적서(COA)

Lot/Batch Number
MKCT2527
MKCV2215
MKCR9911
MKCS4264
STBC6522V

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문서 라이브러리 방문

Sunil Sabbani et al.
Bioorganic & medicinal chemistry letters, 18(21), 5804-5808 (2008-10-11)
Dispiro N-Boc-protected 1,2,4-trioxane 2 was synthesised via Mo(acac)(2) catalysed perhydrolysis of N-Boc spirooxirane followed by condensation of the resulting beta-hydroperoxy alcohol 10 with 2-adamantanone. N-Boc 1,2,4-trioxane 2 was converted to the amine 1,2,4-trioxane hydrochloride salt 3 which was subsequently used
Matthew M Meyer et al.
The Journal of organic chemistry, 75(12), 4274-4279 (2010-05-26)
Deprotonation of 2-adamantanone (1) in the gas phase affords the corresponding beta-enolate anion. This ion was independently prepared by the fluoride-induced desilylation of 4-trimethylsilyl-2-adamantanone, and its reactivity and thermodynamic properties were measured (DeltaH degrees(acid) = 394.7 +/- 1.4, EA =
Hassen Jaafar et al.
Dalton transactions (Cambridge, England : 2003), 40(1), 92-106 (2010-11-19)
We report that the oxygen sensitivity of some Fe(II) complexes with tripodal ligands can be used, with benefit, in the oxidation of cyclohexane under mild conditions. Depending on the solvent, two very different reaction pathways are involved, which share the
Yulan Chen et al.
Nature chemistry, 4(7), 559-562 (2012-06-22)
Nature uses mechanochemical transduction processes to achieve diverse and vital functions, such as hearing, cellular adhesion and gating of ion channels. One fascinating example of biological mechanotransduction is the emission of light on mechanical stimulation. However, molecular-level transduction of force
Irina S Toulokhonova et al.
Journal of the American Chemical Society, 126(17), 5336-5337 (2004-04-29)
Reaction of 1,1-dilithio-1-sila-2,3,4,5-tetraphenylsilole with 2-adamantanone produces a 5-silafulvene. This represents a new method for synthesis of silenes, leading to the first example of a silapentafulvene.
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