666564

N-XantPhos

97%

• 동의어(들): NiXantphos, 4,6-Bis(diphenylphosphino)-10H-phenoxazine, 4,6-Bis(diphenylphosphino)phenoxazine
• Linear Formula: (C₆H₃)₂NHO(P(C₆H₅)₂)₂
• CAS Number: 261733-18-0
• Molecular Weight: 551.55
• MDL number: MFCD03788937
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24884806
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 반응 적합성: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• mp: 256-262 °C
• 작용기: phosphine
• 저장 온도: 2-8°C
• SMILES string: N1c2cccc(P(c3ccccc3)c4ccccc4)c2Oc5c1cccc5P(c6ccccc6)c7ccccc7
• InChI: 1S/C36H27NOP2/c1-5-15-27(16-6-1)39(28-17-7-2-8-18-28)33-25-13-23-31-35(33)38-36-32(37-31)24-14-26-34(36)40(29-19-9-3-10-20-29)30-21-11-4-12-22-30/h1-26,37H
• InChI key: HSWZLYXRAOXOLL-UHFFFAOYSA-N

설명

애플리케이션

N-XantPhos is a deprotonatable chelating aryldiphosphine ligand that can be used in:

• The preparation of Pd-NiXantphos catalyst system for the room temperature cross-coupling reactions of unactivated aryl chlorides.[1]
• The synthesis of cinchonine iridium(III) cyclometalated complex that exhibits luminescence and good quantum efficiency.[2]
• N-XantPhos and N-modified counterparts are also used in the preparation of rhodium based catalysts for hydroformylation reaction.[3]

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable