665479
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)piperidine
97%
동의어(들):
(S)-(+)-4-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-piperidine, (S)-PipPhos
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C25H22NO2P
Molecular Weight:
399.42
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
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추천 제품
![(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine 95% (HPLC)](/deepweb/assets/sigmaaldrich/product/structures/366/790/7555ef31-5d0b-45c9-ad40-5dfd0fe85125/640/7555ef31-5d0b-45c9-ad40-5dfd0fe85125.png)
![(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl)methylamine 97%](/deepweb/assets/sigmaaldrich/product/structures/367/257/41c61b2f-4574-4501-8e80-2ded7f5618a7/640/41c61b2f-4574-4501-8e80-2ded7f5618a7.png)
![(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97%](/deepweb/assets/sigmaaldrich/product/structures/223/794/16c37a96-da16-488a-b3e8-7d89c47f71ee/640/16c37a96-da16-488a-b3e8-7d89c47f71ee.png)
![(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine ≥95% (elemental analysis)](/deepweb/assets/sigmaaldrich/product/structures/575/489/d54360f9-5a59-43f2-bc44-42f5fa92b588/640/d54360f9-5a59-43f2-bc44-42f5fa92b588.png)
![(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4- a′]dinaphthalen-4-yl)dimethylamine 97%](/deepweb/assets/sigmaaldrich/product/structures/400/008/628143de-3954-440a-ba9c-4c0ff8e44663/640/628143de-3954-440a-ba9c-4c0ff8e44663.png)
![(3aR,8aR)-(−)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine 96%](/deepweb/assets/sigmaaldrich/product/structures/218/795/c536ff4e-370b-48fc-b22a-4120030fbfbb/640/c536ff4e-370b-48fc-b22a-4120030fbfbb.png)
![(S,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)-(1-phenylethyl)amine 96%](/deepweb/assets/sigmaaldrich/product/structures/340/157/5071e653-a834-4559-9aa7-4eb2d3774e42/640/5071e653-a834-4559-9aa7-4eb2d3774e42.png)
분석
97%
양식
solid
mp
206-213 °C
SMILES string
C1CCN(CC1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56
InChI
1S/C25H22NO2P/c1-6-16-26(17-7-1)29-27-22-14-12-18-8-2-4-10-20(18)24(22)25-21-11-5-3-9-19(21)13-15-23(25)28-29/h2-5,8-15H,1,6-7,16-17H2
InChI key
ZYDGLCZCEANEHK-UHFFFAOYSA-N
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
가장 최신 버전 중 하나를 선택하세요:
Natasa Mrsić et al.
Journal of the American Chemical Society, 131(24), 8358-8359 (2009-06-18)
Asymmetric hydrogenation of N-aryl acetophenone imines using iridium/PipPhos leads to very high enantioselectivities up to >99% depending on the presence of electron-donating substituents in the 2-, 3-, and 5-position of the aryl ring. If the substituent is 2-methoxy, the resultant
Journal of Organometallic Chemistry, 692, 428-428 (2007)
문서
DSM collaboration offers MonoPhos™ ligands for research, based on the BINOL platform by Feringa and co-workers.
활성 필터
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
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