665460

(3aR,8aR)-(−)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

96%

• 실험식(Hill 표기법): C₃₃H₃₄NO₄P
• CAS Number: 213843-90-4
• Molecular Weight: 539.60
• MDL number: MFCD04117685
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24884738
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 96%
• 양식: solid
• mp: 218-221 °C
• 작용기: amine; ether; ketal; phenyl
• SMILES string: CN(C)P1OC([C@@H]2OC(C)(C)O[C@H]2C(O1)(c3ccccc3)c4ccccc4)(c5ccccc5)c6ccccc6
• InChI: 1S/C33H34NO4P/c1-31(2)35-29-30(36-31)33(27-21-13-7-14-22-27,28-23-15-8-16-24-28)38-39(34(3)4)37-32(29,25-17-9-5-10-18-25)26-19-11-6-12-20-26/h5-24,29-30H,1-4H3/t29-,30-/m1/s1
• InChI key: DRPNADVMTMEWQY-LOYHVIPDSA-N

설명

애플리케이션

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Phosphoramidite ligand employed in an asymmetric, iridium-catalyzed, allylic allylation of propenylboronates. Also used in a copper-catalyzed asymmetric conjugate addition of diethylzinc to α,β-unsaturated imines derived from amino acids.

법적 정보

Sold under license from DSM for research purposes only.

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)