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Merck
모든 사진(1)

주요 문서

654213

Sigma-Aldrich

2-Methylpyridine borane complex

2-Methylpyridine borane complex

95%

동의어(들):

2-Picoline borane complex

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크기 선택

5 G
₩138,040

₩138,040


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5 G
₩138,040

About This Item

CAS Number:
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
NACRES:
NA.22

₩138,040


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벌크 견적 요청

Quality Level

분석

95%

양식

solid

반응 적합성

reagent type: reductant

저장 온도

2-8°C

SMILES string

CC1=NC=CC=C1.B

InChI

1S/C6H7N.B/c1-6-4-2-3-5-7-6;/h2-5H,1H3;

InChI key

QHXLIQMGIGEHJP-UHFFFAOYSA-N

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일반 설명

2-Methylpyridine borane complex is a nontoxic alternate to the reducing agent sodium cyanoborohydride.[1]

애플리케이션

2-Methylpyridine borane complex solution (2-Picoline borane complex) was used as reducing agent for the labeling of oligosaccharides by reductive amination.[2] It may be used in the following studies:
  • Synthesis of alkoxyamine derivatives, via reduction of oxime ethers.[3]
  • Reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones.[4]
  • Synthesis of various trifluoromethylated amino compounds.[5]
  • An alternative reagent for reductive aminations.[6]
Environmentally benign reducing agent

Reactant for:
Reductive amination
N-Benzyl-protection of amino acid derivatives by reductive alkylation
Reductive alkoxyamination

픽토그램

FlameExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

표적 기관

Respiratory system

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point (°F)

212.0 °F - closed cup

Flash Point (°C)

100 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Trifluoroacetaldehyde: A useful industrial bulk material for the synthesis of trifluoromethylated amino compounds.
Mimura H, et al.
Journal of Fluorine Chemistry, 131(4), 477-486 (2010)
One-pot synthesis of alkoxyamine derivatives by reductive alkoxyamination with a 2-picoline-borane complex.
Kawase Y , et al.
Heterocycles, 78(2), 463-470 (2009)
Maaike M Appeldoorn et al.
Carbohydrate research, 381, 33-42 (2013-09-24)
In order to use corn fiber as a source for bioethanol production the enzymatic hydrolysis of the complex glucuronoarabinoxylans present has to be improved. Several oligosaccharides present in the supernatant of mild acid pretreated and enzymatically saccharified corn fiber that
Shigehisa Uchiyama et al.
Analytical chemistry, 81(1), 485-489 (2008-12-06)
A new method for the determination of carbonyls in air using 2,4-dinitrophenylhydrazine (DNPH) has been developed. The traditional method for the measurement of carbonyl compounds, using DNPH to form the corresponding 2,4-dinitrophenylhydrazone (DNPhydrazone) derivatives, is subject to analytical errors because
Sato, S. et al
Tetrahedron, 60, 7899-7899 (2004)

문서

2-picoline-borane (pic-BH3) is an excellent alternative reagent for reductive aminations.

Learn about the applications of chiral oxazaborolidinium ions (COBIs) as Lewis acid catalysts in different asymmetric reactions such as cyclopropanation, epoxidation, and radical reactions along with details of their catalytic action.

질문

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활성 필터

  1. Cambridge, MA
    • 상품평 1
    • 투표 2
    별 5개 중 5개입니다.

    2-Methylpyridine complex

    Reagent came promptly and was properly sealed and worked as desired

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