561762

4-Thioanisolemagnesium bromide solution

0.5 M in THF

• Linear Formula: H₃CSC₆H₄MgBr
• CAS Number: 18620-04-7
• Molecular Weight: 227.40
• MDL number: MFCD00672010
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24879970
• NACRES: NA.22

속성

• 반응 적합성: reaction type: Grignard Reaction
• 농도: 0.5 M in THF
• bp: 65 °C
• density: 0.965 g/mL at 25 °C
• 저장 온도: 2-8°C
• SMILES string: CSc1ccc([Mg]Br)cc1
• InChI: 1S/C7H7S.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
• InChI key: SSVQCUSLJVVRCA-UHFFFAOYSA-M

설명

애플리케이션

4-Thioanisolemagnesium bromide can be used to prepare:

• 3,3-Ethylenedioxy-5a-hydroxy-11b-[4-(thiomethoxy)phenyl]-estr-9-en-17-one, a key intermediate for the synthesis of mifepristone analogs.[1]
• (1S)-1,4-Anhydro-2,3,5,6-tetra-O-benzyl-1-C-[4-chloro-3-(4-methylthiobenzyl)-phenyl]-D-glucitol, a key intermediate for the synthesis of aryl D-glucofuranosides as potent hSGLT2 and hSGLT1 inhibitors.[2]

법적 정보

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS05,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302,H314,H335,H336,H351
• 예방조치 성명서: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 표적 기관: Central nervous system, Respiratory system
• 보충제 위험성: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 1.4 °F
• Flash Point (°C): -17 °C