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5 G
₩248,980
About This Item
실험식(Hill 표기법):
C7H9F3O3S
CAS Number:
Molecular Weight:
230.20
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
![Thieno[3,2-b]thiophene-2,5-dicarboxaldehyde 96%](/deepweb/assets/sigmaaldrich/product/structures/137/771/57dfbc98-f02d-4773-bc11-3e8b861ad74b/640/57dfbc98-f02d-4773-bc11-3e8b861ad74b.png)
![Thieno[3,2-b]thiophene 95%](/deepweb/assets/sigmaaldrich/product/structures/353/609/429fd4bf-e217-4371-80a3-9e5a4d88908b/640/429fd4bf-e217-4371-80a3-9e5a4d88908b.png)
Quality Level
분석
97%
bp
84-87 °C/4 mmHg (lit.)
density
1.315 g/mL at 25 °C (lit.)
작용기
fluoro
triflate
저장 온도
2-8°C
SMILES string
FC(F)(F)S(=O)(=O)OC1=CCCCC1
InChI
1S/C7H9F3O3S/c8-7(9,10)14(11,12)13-6-4-2-1-3-5-6/h4H,1-3,5H2
InChI key
WVSCRRLWRRANJY-UHFFFAOYSA-N
관련 카테고리
일반 설명
1-Cyclohexenyl trifluoromethanesulfonate, also known as 1-cyclohexenyl triflate, is a cyclohexenyl sulfonate. Its trifluoromethylation reaction in the presence of different monodentate biaryl phosphine ligands has been investigated.[1] The asymmetric Heck reaction of 1-cyclohexenyl trifluoromethanesulfonate using palladium complexes of phosphine oxazoline ligand has been studied.[2]
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
160.0 °F - closed cup
Flash Point (°C)
71.1 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Proline derived phosphine-oxazoline ligands in the asymmetric Heck reaction.
Gilbertson SR, et al.
Tetrahedron Letters, 42(3), 365-368 (2001)
Eun Jin Cho et al.
Organic letters, 13(24), 6552-6555 (2011-11-25)
A method for the palladium-catalyzed trifluoromethylation of cyclohexenyl sulfonates has been developed. Various cyclohexenyl triflates and nonaflates underwent trifluoromethylation under mild reaction conditions using a catalyst system composed of Pd(dba)(2) or [(allyl)PdCl](2) and the monodentate biaryl phosphine ligand (t)BuXPhos. The
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