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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
479500
1,2-Bis(dicyclohexylphosphino)ethane
동의어(들):
Ethylenebis(dicyclohexylphosphine), 1,2-Ethanediylbis[dicyclohexyl]phosphine
크기 선택
About This Item
추천 제품
양식
solid
Quality Level
반응 적합성
reagent type: ligand
reaction type: Decarboxylations
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
mp
92.5-96.5 °C (lit.)
작용기
phosphine
SMILES string
C1CCC(CC1)P(CCP(C2CCCCC2)C3CCCCC3)C4CCCCC4
InChI
1S/C26H48P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h23-26H,1-22H2
InChI key
BOUYBUIVMHNXQB-UHFFFAOYSA-N
애플리케이션
- Pd-catalyzed decarbonylative C-H coupling of azoles and aromatic esters.[1]
- Ni-catalyzed cross-coupling reaction of aryl fluorides and primary amines.[2]
- Investigations of the role of ligand-based steric effects during the polymerization
- Synthesis of molybdenum nitrosyl complexes for use as Imine hydrogenation catalysts
- Irreversible thermal linkage isomerization of switchable C-N-bound isomers
- Chelating for conversion of trans complexes to cis complexes
Precursor for Iridium trisboryl complexes and the substituent effect on borylation reactions
Ligand for palladium(II) complex catalyzed hydrogenation reactions
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
>230.0 °F - closed cup
Flash Point (°C)
> 110 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
이미 열람한 고객
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How is shipping temperature determined? And how is it related to the product storage temperature?
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도움이 되었습니까?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf도움이 되었습니까?
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