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Merck
모든 사진(2)

주요 문서

436372

Sigma-Aldrich

4,4′-Diaminodiphenyl sulfide

98%

동의어(들):

4,4′-Thiodianiline

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25 G
₩427,112

₩427,112


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25 G
₩427,112

About This Item

Linear Formula:
S(C6H4NH2)2
CAS Number:
Molecular Weight:
216.30
Beilstein:
1875513
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

₩427,112


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Quality Level

분석

98%

양식

solid

mp

105-107 °C (lit.)

작용기

thioether

SMILES string

Nc1ccc(Sc2ccc(N)cc2)cc1

InChI

1S/C12H12N2S/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2

InChI key

ICNFHJVPAJKPHW-UHFFFAOYSA-N

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일반 설명

4,4′-Diaminodiphenyl sulfide is a diaminodiphenyl analog. On oral administration to rats, it induces haematological and pathological changes indicative of erythrocyte destruction.[1] It has been reported to generate hydrogen peroxide in erythrocytes in vitro.[2] Enzymatic oxidation of 4,4′-diaminodiphenyl sulfide to their sulfoxide derivatives in guinea pig liver homogenates has been reported.[3]

애플리케이션

4,4′-Diaminodiphenyl sulfide may be employed for the fabrication of quantum wires and quantum dots by chemical vapor deposition.[4]
It may be used for the preparation of the following:
  • polypyromellitimides[5]
  • sulfur-containing copolyimides[6]
  • polyamides[7]

픽토그램

Health hazardExclamation markEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

R Munday
Journal of applied toxicology : JAT, 5(6), 409-413 (1985-12-01)
Diphenyl disulphide has been shown to generate hydrogen peroxide in erythrocytes in vitro. It also induces oxidative damage (reversible and irreversible haemoglobin oxidation, depletion of non-protein and protein-bound thiols) in these cells. Such changes were also recorded in erythrocytes exposed
Polycondensation of pyridine-2,6-dicarboxylic acid with some di-and tetraamino compounds.
Banihashemi A and Eghbali M.
Journal of Polymer Science, 14(11), 2659-2664 (1976)
The enzymatic formation of sulfoxides: the oxidation of chlorpromazine and 4,4'-diaminodiphenyl sulfide by guinea pig liver microsomes.
J R GILLETTE et al.
The Journal of pharmacology and experimental therapeutics, 130, 262-267 (1960-11-01)
R Munday et al.
Journal of applied toxicology : JAT, 5(6), 414-417 (1985-12-01)
Diphenyl disulphide, 4,4'-diaminodiphenyl disulphide, 2,2'-diaminodiphenyl disulphide, 4,4'-dimethyldiphenyl disulphide and 4,4'-dinitrodiphenyl disulphide, when administered orally to rats, induced haematological and pathological changes indicative of erythrocyte destruction in vivo. No evidence of haemolysis was detected, however, in animals receiving diphenyl disulphide-2,2'-dicarboxylic acid
Quantum wire and dot formation by chemical vapor deposition and molecular layer deposition of one-dimensional conjugated polymer.
Yoshimura T, et al.
Applied Physics Letters, 60(3), 268-270 (1992)

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