43088

Diphenyliodonium chloride

≥98.0% (AT)

• 동의어(들): DPI, NSC 134275
• Linear Formula: (C₆H₅)₂I⁺Cl^-
• CAS Number: 1483-72-3
• Molecular Weight: 316.57
• Beilstein: 3574977
• EC Number: 216-049-8
• MDL number: MFCD00011909
• UNSPSC 코드: 12352002
• PubChem Substance ID: 57650143
• NACRES: NA.22

속성

• Quality Level: 200
• 분석: ≥98.0% (AT)
• 반응 적합성: reagent type: oxidant
• mp: 233-235 °C (subl.) (lit.)
• 작용기: iodo
• SMILES string: [Cl-].[I+](c1ccccc1)c2ccccc2
• InChI: 1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1
• InChI key: RSJLWBUYLGJOBD-UHFFFAOYSA-M

설명

애플리케이션

Reactant for:

• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
• Synthesis of acetylenic arylselenides
• Sonogashira coupling reactions for the preparation of aryl alkynes
• C-H functionalization for synthesis of (arylmethylene)oxindoles
• Arylation of anilines
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators

기타 정보

Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates[1][2][3]

안전성 정보

• 픽토그램: GHS06
• 신호어: Danger
• 유해 및 위험 성명서: H301,H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges