모든 사진(1)
About This Item
실험식(Hill 표기법):
C9H13NO2
CAS Number:
Molecular Weight:
167.21
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
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추천 제품
분석
98%
양식
liquid
refractive index
n20/D 1.4685 (lit.)
bp
91-92 °C/20 mmHg (lit.)
density
1 g/mL at 25 °C (lit.)
SMILES string
CC(C)(C)OC(=O)n1cccc1
InChI
1S/C9H13NO2/c1-9(2,3)12-8(11)10-6-4-5-7-10/h4-7H,1-3H3
InChI key
IZPYBIJFRFWRPR-UHFFFAOYSA-N
일반 설명
N-Boc-pyrrole is an N-protected pyrrole. It undergoes Diels–Alder reaction with enantiomerically pure allene-1,3-dicarboxylates to form endo-adducts with retention in configurations at two newly generated stereogenic centers.[1] It also undergoes cyclopropanation with methyl phenyldiazoacetate to form both monocyclopropane and dicyclopropane.[2] Its Ir-catalyzed C-H borylation followed by cross coupling with 3-chlorothiophene to form biheterocycle has been reported.[3]
애플리케이션
N-Boc-pyrrole was used in the synthesis of 1-(tert-butoxycarbonyl)-1H-pyrrol-2-ylboronic acid by treating with n-BuLi and subsequent reaction with trimethyl borate.[4]
It may be used as starting material in the synthesis of the following:
It may be used as starting material in the synthesis of the following:
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
167.0 °F - closed cup
Flash Point (°C)
75 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
CuO/SiO2 as a simple, effective and recoverable catalyst for alkylation of indole derivatives with diazo compounds.
Fraile JM, et al.
Organic & Biomolecular Chemistry, 11(26), 4327-4332 (2013)
Venkata A Kallepalli et al.
The Journal of organic chemistry, 74(23), 9199-9201 (2009-11-10)
Ir-catalyzed C-H borylation is found to be compatible with Boc protecting groups. Thus, pyrroles, indoles, and azaindoles can be selectively functionalized at C-H positions beta to N. The Boc group can be removed on thermolysis or left intact during subsequent
Recent progress in the synthesis of five-membered heterocycle boronic acids and esters.
Primas N, et al.
Tetrahedron, 66(41), 8121-8136 (2010)
Nikola Basarić et al.
Organic & biomolecular chemistry, 3(15), 2755-2761 (2005-07-21)
Two fluorescent off-on Ca2+ indicators based on APTRA (o-aminophenol-N,N,O-triacetic acid) as low-affinity ligand for Ca2+ and BODIPY(4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) as a fluorophore were synthesized. The new BODIPY-APTRA compounds absorb in the visible spectrum, with absorption maxima from 505 nm to 570 nm
Huw M L Davies et al.
Chemical Society reviews, 38(11), 3061-3071 (2009-10-23)
The metal catalyzed reactions of diazo compounds have been broadly used in organic synthesis. The resulting metal-carbenoid intermediates are capable of undergoing a range of unconventional reactions, and due to their high energy, they are ideal for initiating cascade sequences
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