185922

Furan

≥99%

• 동의어(들): 1,4-Epoxybuta-1,3-diene, Divinylene oxide, Oxacyclopentadiene, Oxole, Tetrole
• 실험식(Hill 표기법): C₄H₄O
• CAS Number: 110-00-9
• Molecular Weight: 68.07
• Beilstein: 103221
• EC Number: 203-727-3
• MDL number: MFCD00003222
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24851189
• NACRES: NA.22

속성

• vapor density: 2.35 (vs air)
• Quality Level: 100
• vapor pressure: 1672 mmHg ( 55 °C); 31.66 psi ( 55 °C); 493 mmHg ( 20 °C); 9.22 psi ( 20 °C)
• 분석: ≥99%
• 양식: liquid
• 포함: 0.025 wt. % BHT as inhibitor
• expl. lim.: 14.3 %
• refractive index: n20/D 1.421 (lit.)
• bp: 32 °C/758 mmHg (lit.)
• solubility: alcohols: freely soluble; diethyl ether: freely soluble; water: insoluble
• density: 0.936 g/mL at 25 °C (lit.)
• 배송 상태: wet ice
• 저장 온도: 2-8°C
• SMILES string: c1ccoc1
• InChI: 1S/C4H4O/c1-2-4-5-3-1/h1-4H
• InChI key: YLQBMQCUIZJEEH-UHFFFAOYSA-N

설명

일반 설명

Furan is a five membered heterocyclic compound that is highly volatile, flammable and a potential carcinogen.[1] It undergoes Diels-Alder reaction with 2-bromoacrolein catalyzed by oxazaborolidine to yield chiral 7-oxabicyclo[2.2.1]heptene derivatives.[2] Cationic bis(4-tert-butyloxazoline)Cu(II) complex catalyzed enantioselective Diels-Alder reaction between acryloyl oxazolidinone and furan to afford ent-shikimic acid has been described.[3] Lewis acid catalyzed Diels-Alder reaction between furan and some dienophiles affords substituted cyclohexenols and cyclohexadienols.[4]

애플리케이션

Furan was used in the following processes:

• Preparation of the starting material required for the synthesis of calix[6]pyrrole.[5]
• To investigate the kinetics and mechanism of reactions of chlorine atoms with volatile organic compounds.[6]
• Catalytic transformation of furan to aromatics and olefins.[7][8]

안전성 정보

• 픽토그램: GHS02,GHS08,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H224,H302 + H332,H315,H341,H350,H373,H412
• 예방조치 성명서: P210 - P233 - P273 - P304 + P340 + P312 - P308 + P313 - P403 + P233
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 1 - Muta. 2 - Skin Irrit. 2 - STOT RE 2
• 보충제 위험성: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -32.8 °F - closed cup
• Flash Point (°C): -36 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves