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Merck
모든 사진(1)

주요 문서

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423807

Sigma-Aldrich

5-Hydroxy-2-adamantanone

98%

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모든 사진(1)

About This Item

실험식(Hill 표기법):
C10H14O2
CAS Number:
20098-14-0
Molecular Weight:
166.22
MDL number:
MFCD00192211
UNSPSC 코드:
12352100
PubChem Substance ID:
24866531
NACRES:
NA.22

분석

98%

양식

solid

mp

>300 °C (lit.)

작용기

hydroxyl
ketone

SMILES string

O[C@]12C[C@@H]3C[C@H](C1)C(=O)[C@@H](C3)C2

InChI

1S/C10H14O2/c11-9-7-1-6-2-8(9)5-10(12,3-6)4-7/h6-8,12H,1-5H2/t6-,7-,8+,10-

InChI key

TZBDEVBNMSLVKT-XYYXLIQBSA-N

일반 설명

5-Hydroxy-2-adamantanone is a disubstituted derivative of adamantane.[1] The biocatalyzed synthesis of 5-hydroxy-2-adamantanone from 2-adamantanone has been investigated.[2]

애플리케이션

5-Hydroxy-2-adamantanone may be used in the following studies:
  • As a model compound to investigate the application of lanthanide NMR shift reagents for the analysis of disubstituted derivative of adamantane.[1]
  • As a starting material for the synthesis of E-2-amino-5-hydroxyadamantane.[3]
  • As a starting material for the synthesis of 4-(triphenylsilyloxy)adamantan-1-ol.[4]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)

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시험 성적서(COA)

Lot/Batch Number
MKCN0955
MKBC8866
MKAA2767
00818AJ
05811JE

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문서 라이브러리 방문

S S Boĭko et al.
Farmakologiia i toksikologiia, 54(1), 57-59 (1991-01-01)
The pharmacokinetics of a new Soviet-made immunostimulant kemantane, a derivative of adamantine, was studied by gas-liquid chromatography in patients with bronchial pathology. It was found that in the blood of the patients kemantane was not practically detected due to a
[The immunomodulator kemantan in the treatment of patients with exacerbated chronic obstructive bronchitis].
E M Rekalova
Likars'ka sprava, (4)(4), 73-76 (1992-04-01)
An expeditious preparation of E-2-amino-5-hydroxyadamantane and its Z-isomer.
Jaroskova L, et al.
Tetrahedron Letters, 47(46), 8063-8067 (2006)
Biocatalytic production of 5-hydroxy-2-adamantanone by P450cam coupled with NADH regeneration.
Furuya T, et al.
Journal of Molecular Catalysis. B, Enzymatic, 94, 111-118 (2013)
S S Boĭko et al.
Eksperimental'naia i klinicheskaia farmakologiia, 57(6), 48-50 (1994-11-01)
The pharmacokinetics of the new immunostimulant kemantane, adamantane derivative, used in two species of animals (rats and rabbits) and man was studied. There were significant differences in the pharmacokinetics of kemantane and its active metabolite--adamantane-1,4-diol between the species.
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