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Merck
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주요 문서

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391638

Sigma-Aldrich

Dimethylphosphoramidous dichloride

97%

동의어(들):

(Dichlorophosphanyl)dimethylamine, (Dimethylamino)dichlorophosphine, Dichloro(dimethylamido)phosphorus, Dichloro(dimethylamino)phosphine, Dichloro-N,N-dimethylaminophosphine, N,N-Dimethylphosphoramidous dichloride

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크기 선택

25 ML
₩244,818

₩244,818

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청
모든 사진(1)

크기 선택

보기 변경
25 ML
₩244,818

About This Item

Linear Formula:
(CH3)2NPCl2
CAS Number:
683-85-2
Molecular Weight:
145.96
MDL number:
MFCD00013613
UNSPSC 코드:
12352100
PubChem Substance ID:
24864392
NACRES:
NA.22

₩244,818

구입 가능 여부는 고객센터에 문의하십시오.
벌크 견적 요청

Quality Level

100

분석

97%

양식

liquid

refractive index

n20/D 1.505 (lit.)

bp

150 °C (lit.)

density

1.271 g/mL at 25 °C (lit.)

작용기

amine

저장 온도

2-8°C

SMILES string

CN(C)P(Cl)Cl

InChI

1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3

InChI key

XPWWDZRSNFSLRQ-UHFFFAOYSA-N

관련 카테고리

일반 설명

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative.[1] It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry.[2] Its synthesis has been reported.[3] Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms.[1] Its vibrational spectra has been studied.[4] Its reaction with SO2 has been investigated.[5] It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.[6]

애플리케이션

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
  • N,N-dimethylamidotetrachlorophosphorane[7]
  • O-propylchloroformimino-N,N-dimethylamidochlorophosphate[7]
  • 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines[8]

픽토그램

FlameCorrosion
GHS02,GHS05

신호어

Danger

유해 및 위험 성명서

H225,H314

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

보충제 위험성

EUH014

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

-9.4 °F - closed cup

Flash Point (°C)

-23 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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시험 성적서(COA)

Lot/Batch Number
MKBW3143V
MKBQ3660V
MKBJ7543V
01117EE
S34766

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문서 라이브러리 방문

Vibrational spectra and structure of dimethylaminodichlorophosphine.
Durig JR and Casper JM
The Journal of Physical Chemistry, 75(25), 3837-3843 (1971)
Equilibrium conformation of dimethylaminodichlorophosphine molecule: the use of the results of quantum-chemical calculations and spectroscopic measurements in the analysis of gas-phase electron diffraction data.
Khaikin LS, et al.
Russian Chemical Bulletin, 50(9), 1550-1562 (2001)
Dimethylaminodimethylphosphine1.
Burg AB and Slota Jr PJ.
Journal of the American Chemical Society, 80(5), 1107-1109 (1958)
Reactions of sulfur dioxide with aminophosphines.
Light RW and Paine RT.
Phosph. Sulfur Relat. Elem., 8(3), 255-258 (1980)
G K Surya Prakash et al.
Proceedings of the National Academy of Sciences of the United States of America, 107(36), 15693-15698 (2010-08-21)
It is difficult to overestimate the importance of nucleoside triphosphates in cellular chemistry: They are the building blocks for DNA and RNA and important sources of energy. Modifications of biologically important organic molecules with fluorine are of great interest to
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