365270

Methyl α-bromophenylacetate

97%

• Linear Formula: C₆H₅CH(Br)CO₂CH₃
• CAS Number: 3042-81-7
• Molecular Weight: 229.07
• MDL number: MFCD00013535
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24862500
• NACRES: NA.22

속성

• 분석: 97%
• 양식: liquid
• refractive index: n20/D 1.553 (lit.)
• bp: 113 °C/3 mmHg (lit.)
• density: 1.455 g/mL at 25 °C (lit.)
• 작용기: bromo; ester; phenyl
• 저장 온도: 2-8°C
• SMILES string: COC(=O)C(Br)c1ccccc1
• InChI: 1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
• InChI key: NHFBYYMNJUMVOT-UHFFFAOYSA-N

설명

일반 설명

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.[1]

애플리케이션

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA).[2] It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.[3]

안전성 정보

• 픽토그램: GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H314
• 예방조치 성명서: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• Hazard Classifications: Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point (°F): 235.4 °F - closed cup
• Flash Point (°C): 113 °C - closed cup
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter