323373

Palladium(II) chloride

99.995%

• 동의어(들): Dichloropalladium, Palladium dichloride, Palladous chloride
• 실험식(Hill 표기법): Cl₂Pd
• CAS Number: 7647-10-1
• Molecular Weight: 177.33
• EC Number: 231-596-2
• MDL number: MFCD00003558
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24859361
• NACRES: NA.22

속성

• 분석: 99.995%
• 형태: powder
• 반응 적합성: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 678-680 °C (lit.)
• density: 4 g/mL at 25 °C (lit.)
• SMILES string: Cl[Pd]Cl
• InChI: 1S/2ClH.Pd/h2*1H;/q;;+2/p-2
• InChI key: PIBWKRNGBLPSSY-UHFFFAOYSA-L

설명

일반 설명

Palladium(II) chloride is used as a precursor to prepare palladium catalysts for various reactions like Heck coupling, cascade reaction, Buchward-Hartwig coupling. It is also used as an oxidizing agent.

애플리케이션

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

Palladium(II) chloride can be used as a catalyst in:

• Carbonylation of ketones to yield diesters.
• Homo-coupling of aryl bromides using ascorbic acid and EDTA..
• Acetylation of alcohols with vinyl acetate.
• Arylation of 2-furaldehyde to yield 5-aryl-2-formylfuran derivatives.

Pd precursor used as an oxidizing agent and as a source of Pd(0) complexes, e.g. Heck coupling, Cascade reaction, Buchward-Hartwig coupling.

안전성 정보

• 픽토그램: GHS05,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H290,H302,H317,H318,H410
• 예방조치 성명서: P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1
• Storage Class Code: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges