234184

Methyl phenylsulfonylacetate

97%

• 동의어(들): Methyl benzenesulfonylacetate
• Linear Formula: C₆H₅SO₂CH₂COOCH₃
• CAS Number: 34097-60-4
• Molecular Weight: 214.24
• Beilstein: 2051463
• MDL number: MFCD00007555
• UNSPSC 코드: 12352100
• PubChem Substance ID: 24854027
• NACRES: NA.22

속성

• 분석: 97%
• refractive index: n20/D 1.535 (lit.)
• bp: 165 °C/0.05 mmHg (lit.)
• density: 1.305 g/mL at 20 °C (lit.)
• 작용기: ester; sulfone
• SMILES string: COC(=O)CS(=O)(=O)c1ccccc1
• InChI: 1S/C9H10O4S/c1-13-9(10)7-14(11,12)8-5-3-2-4-6-8/h2-6H,7H2,1H3
• InChI key: NLEAIFBNKPYTGN-UHFFFAOYSA-N
• 유전자 정보: human ... LOC129293(129293)

설명

애플리케이션

Methyl phenylsulfonylacetate has been used:

• in a key step during the synthesis of (−)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida[1]
• in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium[2]
• in three step synthesis of 2-(hydroxymethyl)indene[3]

안전성 정보

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 172.4 °F - closed cup
• Flash Point (°C): 78 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)