190780
Sodium trichloroacetate
97%
동의어(들):
NaTCA, TCA sodium salt, Trichloroacetic acid sodium salt
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100 G
₩62,423
About This Item
Linear Formula:
CCl3CO2Na
CAS Number:
Molecular Weight:
185.37
Beilstein:
3773249
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
97%
작용기
chloro
SMILES string
[Na+].[O-]C(=O)C(Cl)(Cl)Cl
InChI
1S/C2HCl3O2.Na/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1
InChI key
SAQSTQBVENFSKT-UHFFFAOYSA-M
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애플리케이션
Sodium trichloroacetate with trichloroacetic acid (TCA) undergoes rapid decarboxylation in dimethylformamide (DMF) in the presence of aldehydes to form nucleophilic trichloromethyl anion, which then adds to the aldehydes to form trichloromethyl carbinols.[1] It can also undergo thermal decarboxylation in aprotonic solvents in the presence of olefins to generate dichlorocarbene as an intermediate.[2]
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
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The thermal decarboxylation of alkali trichloroacetates in aprotic solvents. II. Decarboxylation in the presence of olefins.
Wagner WM
Rec. Trav. Chim., 80(7), 740-746 (1961)
Two effective procedures for the synthesis of trichloromethyl ketones, useful precursors of chiral ?-amino and ?-hydroxy acids.
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Tetrahedron Letters, 33(24), 3435-3438 (1992)
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