185884

N,N-Dimethylacetamide

ReagentPlus^®, ≥99%

• 동의어(들): DMAc
• Linear Formula: CH₃CON(CH₃)₂
• CAS Number: 127-19-5
• Molecular Weight: 87.12
• Beilstein: 1737614
• EC Number: 204-826-4
• MDL number: MFCD00008686
• UNSPSC 코드: 12352111
• eCl@ss: 39031204
• PubChem Substance ID: 329751718
• NACRES: NA.21

속성

• vapor density: 3 (vs air)
• Quality Level: 100
• vapor pressure: 2 mmHg ( 25 °C); 4 mmHg ( 38 °C)
• 제품 라인: ReagentPlus^®
• 분석: ≥99%
• 양식: liquid
• autoignition temp.: 914 °F
• expl. lim.: 1.8 %, 100 °F; 11.5 %, 160 °F
• refractive index: n20/D 1.437 (lit.)
• pH: 4 (20 °C, 200 g/L)
• bp: 164.5-166 °C (lit.)
• mp: −20 °C (lit.)
• density: 0.937 g/mL at 25 °C (lit.)
• SMILES string: CN(C)C(C)=O
• InChI: 1S/C4H9NO/c1-4(6)5(2)3/h1-3H3
• InChI key: FXHOOIRPVKKKFG-UHFFFAOYSA-N

설명

일반 설명

N,N-Dimethylacetamide (DMAc) is widely used to compose the solvent mixtures for cellulose. Static and dynamic light scattering studies of the cellulose dissolved in varying concentrations of DMAc/LiCl mixtures have been reported.[1]

애플리케이션

N,N-Dimethylacetamide (DMAc) has been employed as an organic solvent for the liquid-phase exfoliation of pristine graphene from bulk graphite.[2]
It may be used to compose the solvent system along with lithium chloride (LiCl) for the dissolution of commercial rayon grade cellulose.[3] DMAc/LiCl solvent mixtures have been used for the preparation of chitin, cellulose and polyimide fibers and films.[4]

N,N-Dimethylacetamide may be used in the preparation of α-lithio N,N-dimethylacetamide.[5] DMAc along with palladium chloride forms an efficient catalytic system for the oxidation of several internal olefins to carbonyl compounds without undergoing isomerization.[6]

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS08,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H312 + H332,H319,H360D
• 예방조치 성명서: P202 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Repr. 1B
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 2
• Flash Point (°F): 147.2 °F - closed cup
• Flash Point (°C): 64 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter