176206

Poly(methylhydrosiloxane)

average M_n 1,700-3,200

• 동의어(들): Methylhydrogensiloxane polymer, PMHS
• Linear Formula: (CH₃)₃SiO[(CH₃)HSiO]_nSi(CH₃)₃
• CAS Number: 63148-57-2
• MDL number: MFCD00084478
• UNSPSC 코드: 12162002
• PubChem Substance ID: 24850562
• NACRES: NA.23

속성

• 형태: liquid
• 분자량: average M_n 1,700-3,200
• 환경친화적 대안 제품 특성: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• refractive index: n20/D 1.398
• 점도: 12-45 cSt
• density: 1.006 g/mL at 25 °C (lit.)
• 환경친화적 대안 카테고리: , Aligned

설명

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign reducing agent and has been enhanced for catalytic efficiency. Click here for more information.
Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products

애플리케이션

Reducing agent.

Used in greener amine synthesis by reductive amination as an alternative to borohydrides.

Synthesis of substituted amines and isoindolinones: catalytic reductive amination using abundantly available AlCl3/PMHS

Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts

안전성 정보

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 399.2 °F - closed cup
• Flash Point (°C): 204 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)