コンテンツへスキップ
Merck
すべての画像(1)

Key Documents

安全性情報

940348

Dichloro(p-cymene)ruthenium(II) dimer ChemBeads

new

別名:

(p-Cymene)ruthenium(II) chloride dimer ChemBeads, Benzene-1-methyl-4-(1-methylethyl)-ruthenium complex ChemBeads

ログイン組織・契約価格を表示する


About This Item

実験式(ヒル表記法):
C20H28Cl4Ru2
CAS番号:
分子量:
612.39
UNSPSCコード:
12352100

現在、価格および在庫状況を閲覧できません。

形状

solid

品質水準

組成

, 4-6 wt. % (loading)

反応適合性

reagent type: catalyst

SMILES記法

[Cl-][Ru+2]123456([Cl-][Ru+2]789%10%11([Cl-])([Cl-]1)[CH]=%12[CH]%11=C%10(C(C)C)[CH]9=[CH]8C%127C)[CH]=%13[CH]6=C5(C(C)C)[CH]4=[CH]3C%132C

InChI

InChI=1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4

InChI Key

LAXRNWSASWOFOT-UHFFFAOYSA-J

詳細

The ChemBeads product of the (p-Cymene)ruthenium(II) chloride dimer. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE).
Dichloro(p-cymene)ruthenium(II) dimer is commonly used as a ruthenium starting material, and has been used in:
- Bifunctional P-containing RuO2 catalysts prepared from surplus Ru coordination complexes applied to Zn/Air batteries.[1]
- The synthesis of half-sandwich type platinum-group metal complexes of C-glucosaminyl azines.
- The C(sp2)-H bond functionalization along with concomitant (4+2) annulation of coumarin-3-carboxamide.[2]
-The acceptor engineering of ruthenium metallocycles with high phototoxic indices for safer photodynamic therapy.[3]

特徴および利点

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

保管分類コード

11 - Combustible Solids

WGK

WGK 3

引火点(°F)

Not applicable

引火点(℃)

Not applicable


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

Jan Code

940348-1G:
940348-VAR:
940348-BULK:


最新バージョンのいずれかを選択してください:

試験成績書(COA)

Lot/Batch Number

適切なバージョンが見つかりませんか。

特定のバージョンが必要な場合は、ロット番号またはバッチ番号で特定の証明書を検索できます。

以前この製品を購入いただいたことがある場合

文書ライブラリで、最近購入した製品の文書を検索できます。

文書ライブラリにアクセスする

Chonglu Li et al.
Chemical science, 14(11), 2901-2909 (2023-03-21)
Although metallacycle-based photosensitizers have attracted increasing attention in biomedicine, their clinical application has been hindered by their inherent dark toxicity and unsatisfactory phototherapeutic efficiency. Herein, we employ a π-expansion strategy for ruthenium acceptors to develop a series of Ru(ii) metallacycles
Anindita Sarkar et al.
Organic & biomolecular chemistry, 21(27), 5567-5586 (2023-06-26)
Efficacious protocols have been established to synthesize a structurally privileged Π-extended coumarin-fused pyridone nucleus by activating the vinylic C(sp2)-H bond of coumarin-3-carboxamide under the influence of inexpensive Ru(II)-metal. Here an N-methoxy carboxamide entity has been exploited as the chelating fragment
Sebastián Lorca et al.
Nanomaterials (Basel, Switzerland), 13(1) (2023-01-09)
An innovative synthetic route that involves the thermal treatment of selected Ru co-ordination complexes was used to prepare RuO2-based materials with catalytic activity for oxygen reduction (ORR) and oxygen evolution (OER) reactions. Extensive characterization confirmed the presence of Ru metal
Bryan T Ingoglia et al.
Tetrahedron, 75(32), 4199-4211 (2020-01-04)
Over the past three decades, Pd-catalyzed cross-coupling reactions have become a mainstay of organic synthesis. In particular, catalysts derived from biaryl monophosphines have shown wide utility in forming C-N bonds under mild reaction conditions. This work summarizes a variety of
Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of

ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.

製品に関するお問い合わせはこちら(テクニカルサービス)