06061

Allyl phenyl sulfone

purum, ≥98.0% (GC)

• 別名: (2-Propen-1-ylsulfonyl)benzene, (2-Propenylsulfonyl)benzene, (Allylsulfonyl)benzene, Phenyl 2-propenyl sulfone
• 化学式: C₆H₅SO₂CH₂CH=CH₂
• CAS番号: 16212-05-8
• 分子量: 182.24
• Beilstein: 1863561
• EC Number: 240-338-8
• MDL番号: MFCD00014739
• UNSPSCコード: 12352100
• PubChem Substance ID: 329748204
• NACRES: NA.22

特性

• グレード: purum
• 品質水準: 200
• アッセイ: ≥98.0% (GC)
• 形状: liquid
• 屈折率: n20/D 1.548 (lit.); n20/D 1.548
• bp: 110-113 °C/0.5 mmHg (lit.)
• 密度: 1.189 g/mL at 25 °C (lit.)
• 保管温度: 2-8°C
• SMILES記法: C=CCS(=O)(=O)c1ccccc1
• InChI: 1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2
• InChI Key: KYPIULIVYSQNNT-UHFFFAOYSA-N

詳細

アプリケーション

Possible usages of allyl phenyl sulfone:

• It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
• It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
• It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Starting material for the preparation of 1-alkyl-2-methylethenes; Michael additions to enones; Synthesis of α,β-unsaturated nitriles

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315,H319,H335
• 注意書き: P302 + P352 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 235.4 °F - closed cup
• 引火点(℃): 113 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter