655414

2-(2'-ジ-tert-ブチルホスフィン)ビフェニルパラジウム(II)アセタート

97%

• 別名: パラジウム,(アセタト-KO)[2'-[ビス(1,1 ジメチルエチル)ホスフィノ-KP][1,1'-ビフェニル]-2-イル KC]
• 実験式（ヒル表記法）: C₂₂H₂₉O₂PPd
• CAS番号: 577971-19-8
• 分子量: 462.86
• MDL番号: MFCD04117716
• UNSPSCコード: 12352300
• PubChem Substance ID: 24884102
• NACRES: NA.22

特性

• アッセイ: 97%
• 形状: solid
• 反応適合性: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 130-140 °C (dec.) (lit.)
• SMILES記法: CC(=O)[Pd]1c2ccccc2-c3ccccc3[PH]1(C(C)(C)C)C(C)(C)C
• InChI: 1S/C20H26P.C2H4O2.Pd/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2(3)4;/h7-12,14-15H,1-6H3;1H3,(H,3,4);/q;;+1/p-1
• InChI Key: IEYDYAASBZOBOC-UHFFFAOYSA-M

詳細

詳細

2-(2′-Di-tert-butylphosphine)biphenylpalladium(II) acetate is a novel, air- and moisture-and thermally stable catalyst.

アプリケーション

It can be used as a pre-catalyst for the amination of aryl chlorides. It can also be used to prepare N-methyl-6-heterocyclic-1-oxoisoindoline derivatives via Buchwald-Hartwig amination reaction of N-methyl-6- bromoisoindoline-1-one with different amines under microwave condition.

ブッフバルト・ハートウィッグアミノ化のためのプレ触媒

安全性情報

• 保管分類コード: 13 - Non Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)