384321

プロパルギルクロリド 溶液

70 wt. % in toluene

• 別名: 3-クロロ-1-プロピン
• 化学式: HC≡CCH₂Cl
• CAS番号: 624-65-7
• 分子量: 74.51
• Beilstein: 506005
• MDL番号: MFCD00000980
• UNSPSCコード: 12352100
• PubChem Substance ID: 24863662
• NACRES: NA.22

特性

• 形状: liquid
• 濃度: 70 wt. % in toluene
• 屈折率: n20/D 1.456
• 密度: 0.963 g/mL at 25 °C
• 官能基: alkyl halide; chloro
• 保管温度: 2-8°C
• SMILES記法: ClCC#C
• InChI: 1S/C3H3Cl/c1-2-3-4/h1H,3H2
• InChI Key: LJZPPWWHKPGCHS-UHFFFAOYSA-N

詳細

詳細

Product is the 70wt.% solution of propargyl chloride in toluene. Propargyl chloride is a propargyl halide. Its trimethylsilylation reaction has been reported. Liquid-phase Raman spectra, and vapor-phase and solution-phase infrared spectra of propargyl chloride has been studied at 100-3400cm^-1 and 300-3800cm^-1, respectively. It participates in the addition reaction with acyclic 1,3-dienes (at -78°C) in the presence of zinc chloride.

アプリケーション

Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8. It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols.

Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.

安全性情報

• ピクトグラム: GHS02,GHS06,GHS08,GHS05
• シグナルワード: Danger
• 危険有害性情報: H225,H301 + H311 + H331,H304,H314,H336,H361d,H373,H412
• 注意書き: P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
• ターゲットの組織: Central nervous system
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 66.2 °F
• 引火点(℃): 19 °C