334235

(3S-cis)-(+)-Tetrahydro-3-isopropyl-7a-methylpyrrolo[2,1-b]oxazol-5(6H)-one

95%

• 実験式（ヒル表記法）: C₁₀H₁₇NO₂
• CAS番号: 98203-44-2
• 分子量: 183.25
• MDL番号: MFCD00467212
• UNSPSCコード: 12352005
• PubChem Substance ID: 24860069

特性

• アッセイ: 95%
• 形状: liquid
• 光学活性: [α]27/D +90°, c = 2.8 in ethanol
• 屈折率: n20/D 1.473 (lit.)
• bp: 70 °C/0.4 mmHg (lit.)
• 密度: 1.027 g/mL at 25 °C (lit.)
• SMILES記法: CC(C)[C@H]1CO[C@]2(C)CCC(=O)N12
• InChI: 1S/C10H17NO2/c1-7(2)8-6-13-10(3)5-4-9(12)11(8)10/h7-8H,4-6H2,1-3H3/t8-,10-/m1/s1
• InChI Key: NUUDVADIQSLTCN-PSASIEDQSA-N

詳細

アプリケーション

Chiral bicyclic lactams such as this are useful templates for the asymmetric synthesis of a variety of natural and unnatural products. High levels of asymmetric induction have been obtained in cycloadditions, alkylations, conjugate additions, annulations, and dihydroxylations.

安全性情報

• ピクトグラム: GHS02,GHS07
• シグナルワード: Warning
• 危険有害性情報: H226,H315,H319,H335
• 注意書き: P261 - P305 + P351 + P338
• 危険有害性の分類: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): 136.4 °F - closed cup
• 引火点(℃): 58 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter