196436

(1R)-(−)-フェンコン

≥98%

• 別名: (−)-1,3,3-トリメチル-2-ノルボルナノン, (−)-フェンコン, (1R)-1,3,3-トリメチルビシクロ[2.2.1]ヘプタン-2-オン
• 実験式（ヒル表記法）: C₁₀H₁₆O
• CAS番号: 7787-20-4
• 分子量: 152.23
• Beilstein: 2042710
• EC Number: 232-107-5
• MDL番号: MFCD00151104
• UNSPSCコード: 12352200
• PubChem Substance ID: 24851759
• NACRES: NA.22

特性

• アッセイ: ≥98%
• 形状: liquid
• 光学活性: [α]24/D −50.5°, neat
• 屈折率: n20/D 1.461 (lit.)
• bp: 192-194 °C (lit.)
• mp: 5-6 °C (lit.)
• 密度: 0.948 g/mL at 25 °C (lit.)
• SMILES記法: CC1(C)C2CCC(C)(C2)C1=O
• InChI: 1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m0/s1
• InChI Key: LHXDLQBQYFFVNW-OIBJUYFYSA-N

詳細

詳細

(1R)-(-)-Fenchone is a bridged bicyclic ketone found in fennel oil and thuja oil.

アプリケーション

(1R)-(-)-Fenchone undergoes condensation with pyridinylalkylamines to form chiral iminopyridine ligands, which find applications in enantioselective copper-catalyzed Henry (nitro aldol) reaction. It may also be used in the preparation of enantiopure C(7)-anti-substituted fenchones as new chiral sources.

安全性情報

• ピクトグラム: GHS09
• 危険有害性情報: H411
• 注意書き: P273 - P391 - P501
• 危険有害性の分類: Aquatic Chronic 2
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 2
• 引火点(°F): 151.7 °F - closed cup
• 引火点(℃): 66.5 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter