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908886

Sigma-Aldrich

N-Cyano-4-methoxy-picolinimidamide

≥95%

Synonym(s):

Weix ligand

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250 MG
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250 MG
¥21,500
1 G
¥60,100

About This Item

Empirical Formula (Hill Notation):
C8H8N4O
CAS Number:
1988789-96-3
Molecular Weight:
176.18
MDL number:
MFCD32173815
UNSPSC Code:
12352111
NACRES:
NA.22

¥21,500

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Assay

≥95%

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

220-225 °C

SMILES string

N(C(=N)c1nccc(c1)OC)C#N

InChI

1S/C8H8N4O/c1-13-6-2-3-11-7(4-6)8(10)12-5-9/h2-4H,1H3,(H2,10,12)

InChI key

LEWHOCRDELQPCV-UHFFFAOYSA-N

Related Categories

Application

This pyridyl carboxamidine ligand has been demonstrated by Daniel Weix′s lab to enable nickel-catalyzed cross-coupling of diverse basic nitrogen heterocycles with primary and secondary alkyl halides.

Other Notes

New ligands for nickel catalysis from diverse pharmaceutical heterocycle libraries

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

908886-250MG:
908886-VAR:
908886-1G:
908886-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT8895

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Eric C Hansen et al.
Nature chemistry, 8(12), 1126-1130 (2016-11-23)
Ligands are essential for controlling the reactivity and selectivity of reactions catalysed by transition metals. Access to large phosphine ligand libraries has become an essential tool for the application of metal-catalysed reactions industrially, but these existing libraries are not well

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