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925519

Sigma-Aldrich

BpyCAM•HCl

Synonym(s):

2,2′-Bipyridine-6-carboxamidine

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100 MG
¥15,600
500 MG
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About This Item

Empirical Formula (Hill Notation):
C11H11ClN4
CAS Number:
219745-75-2
Molecular Weight:
234.68
MDL number:
MFCD12755605
UNSPSC Code:
12352103
NACRES:
NA.22

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form

powder

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>215 °C

storage temp.

−20°C

SMILES string

NC(C1=CC=CC(C2=CC=CC=N2)=N1)=N.Cl

InChI

1S/C11H10N4.ClH/c12-11(13)10-6-3-5-9(15-10)8-4-1-2-7-14-8;/h1-7H,(H3,12,13);1H

InChI key

DWSUJJYYHWLZMW-UHFFFAOYSA-N

Related Categories

Application

BpyCAM•HCl is a bipyridine carboxamidine ligand that enables nickel-catalyzed cross-electrophile couplings of diverse aryl and alkyl halides.

Other Notes

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

925519-BULK:
925519-500MG:
925519-100MG:
925519-VAR:

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Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of

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