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72023AST

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Astec® CHIRALDEX B-DA Capillary GC Column

L × I.D. 30 m × 0.25 mm, df 0.12 μm

Sinonimo/i:

GC column, chiral, beta-dextran

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About This Item

Codice UNSPSC:
41115710
NACRES:
SB.54

Materiali

fused silica

Descrizione

GC capillary column

Confezionamento

pkg of 1 ea

Parametri

-10-200 °C temperature (isothermal)
-10-220 °C temperature (programmed)

Beta

500

df

0.12 μm

tecniche

gas chromatography (GC): suitable

Lungh. × D.I.

30 m × 0.25 mm

Gruppo funzionale matrice

non-bonded; 2,6-di-O-pentyl-3-methoxy derivative of β-cyclodextrin phase

applicazioni

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

Tipo di colonna

capillary chiral

Tecnica di separazione

chiral

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Descrizione generale

CHIRALDEX B-DA requires that analytes possess a minimum of two ring structures, one of which is unsaturated (aromatic) α, β to the stereogenic center. Examples include fluoxetine, methylphenidate and chloropheniramine. Inclusion complexation or proper fit between the analyte and cyclodextrin cavity is the dominant enantioselectivity mechanism for the DA series. There must be an includable group α or β to the stereogenic center for chiral recognition. Since CHIRALDEX DA columns most effectively separate multi-ring analytes, analysis temperatures are often higher than 150°C. Enantioselectivity has been observed at temperatures >200°C (fluoxetine acetyl derivative).

Resistenza chim/fis

Temp. Limits:
  • -10 °C to 200 °C isothermal, 220 °C programmed

Altre note

We offer a variety of chromatography accessories including analytical syringes

Note legali

Astec is a registered trademark of Merck KGaA, Darmstadt, Germany
CHIRALDEX is a trademark of Sigma-Aldrich Co. LLC

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Structurally informative response patterns of some monoterpenoids found in volatile oils to gas chromatography on two commercial dipentylated cyclodextrin phases
Betts, T.J.
Journal of Chromatography A, 639 (2), 366-370 (1993)

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